A series of various symmetric monomers containing we/a-linkage were studied. Monomers consisted of benzene as core centre with attached thienyl, furyl and EDOT groups. All monomers were electroactive. In the first oxidation step monomers underwent electropolymerization with branched oligomers or polymers formation. Electrical and optical properties of polymers depended on aryls linkers and presence of methoxyl substituent.
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