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EN
Purpose: The paper presents the results of the microstructural and magnetic examinations of Nd-Fe-B type magnets produced by the mechanical powder milling method and doped with tungsten. Design/methodology/approach: The effect of the grain size and addition of tungsten on the microstructure and magnetic properties of nanocrystalline alloys of the basic composition of Nd10Fe84B6, as produced by the method of mechanical alloying in the process of prolonged milling, was investigated in the study. Powders were subjected to milling for a duration ranging from 10 to 120 hours in an Ar protective atmosphere. Moreover tungsten was added to the base alloy that exhibited the best magnetic parameters. The tungsten content of alloys varied in a broad range from 0 to 33 at%. Findings: The examinations have shown that the grinding duration, for which the best magnetic properties are obtained, is 90 hours. Prolonged grinding has a significant effect on the grain size and microstructure refinement. The alloy addition in the form of tungsten, similarly as in the case of prolonged grinding, leads to a structure refinement. In the case of W addition, an increase in the coercive field, with a simultaneous decrease in the value of remanence and magnetic energy density (BH)max, is observed. Practical implications: Development of relatively cheap Nd10Fe84B6 magnets of good service properties. Originality/value: Determination of the effect of grain size and tungsten content on the magnetic properties and microstructure of the Nd-Fe-B magnets.
EN
The nanocomposite Nd2Fe14B/alpha-Fe magnets with different grain size produced by mechanical alloying were studied. The phase composition of the magnets was determined on the basis of X-ray diffraction and Moessbauer spectroscopy. It was stated that the alloy is composed of three phases (with different volume fraction depending on the milling time): the magnetically hard phase Nd2Fe14B and the magnetically soft phases alpha-Fe and Nd2Fe17. In metallographic examinations, the techniques of optical, scanning and transmission electron microscopy were employed. Moreover, magnetic properties were determined depending on milling time (grain size). Maximum magnetic properties were achieved in the magnet produced from powders obtained after 90 hours' milling, which were as follows: Jr=0,914 T; jHc=251.1 kA/m; Js=2.12 T and (BH)max=67.7 kJ/cubic m.
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