Thermo-physical properties are the critical input parameters in computational models of solidification and casting simulations. In thermodynamics, the enthalpy is quotient of thermodynamic potential of a system, which can be used to calculate the useful work obtainable from a closed thermodynamic system under constant pressure. Differential thermal analysis has been used to study melting and solidification paths in the cobalt based superalloy FSX-414. The temperature enthalpy curve was determined from differential thermal analysis curves obtained from solidification curves. A solidification simulation of a cobalt base multi-component alloy casting was carried out to predict cooling and shrinkage porosity in the casting of a turbine engine vane segment. The effect of latent heat on the heat transfer calculation was considered by enthalpy method.
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Very small quantities of polyethylene oxide (PEO) with molecular weight of 600,000 exhibit a non-additive effect of increased permeability that is higher in higher compaction energies (19.62 J). Increased permeability has been proven at such small PEO quantities as 0.0365 %-wt., 0.073 %-wt., and 0.1 %-wt. The above mentioned very small PEO quantities result in slightly increased bondability. It is estimated that PEO effect will find application in metal casting at lower melting temperatures.
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