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Content available remote Far-Infrared Study of DX-Like Centers in Pb_{0.95}Mn_{0.05}Te(Ga)
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EN
We present far-infrared reflection spectra of Pb_{0.95}Mn_{0.05}Te single crystal doped with gallium between 10 and 300 K. The analysis of the far-infrared reflection spectra was made by a fitting procedure based on the model of coupled oscillators. Together with the strong plasmon-phonon coupling we obtain three local modes of gallium at about 122 cm^{-1}, 166 cm^{-1}, and 192 cm^{-1}. The position of these modes depends on impurity center charge, and their intensity depends on temperature.
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Content available remote Ellipsometric Measurements of Plastically Deformed Copper
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EN
Chemically pure copper (99.99) prepared in the sample of square cross-section (10×10 mm^{2}) and length about 50 mm was extremely plastically deformed with the repeated application of equal channel angular pressing. Equal channel angular pressing was applied as an effective technique for producing bulk nanoscaled structures. It is well known that severe plastic deformation of metallic materials often leads to microstructure with ultrafine grains and cross-sections which remain about equal before and after deformation. Optical properties of the sample were studied using spectroscopic ellipsometry in UV-VIS range. The parameters of the sample like copper oxide and surface roughness overlayer were calculated using two-film model together with the Bruggeman effective medium approximation.
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Content available remote Low-Frequency Raman Scattering from ZnO(Fe) Nanoparticles
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Nanocrystalline samples of ZnO(Fe) were synthesized by wet chemical method. Samples were characterized by X-ray diffraction to determine the sample composition and the mean crystalline size. Low-frequency Raman modes were measured and assigned according to confined acoustic vibrations of spherical nanoparticles. Frequencies of these vibrational modes were analyzed in elastic continuum aproximation, which considers nanoparticle as homogeneous elastic sphere.
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Content available remote Nanocrystalline ZnO Doped with Fe_2O_3 - Magnetic and Structural Properties
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We have studied the magnetic properties of ZnO nanocrystals doped with Fe_2O_3 in the magnetic dopant range from 5 to 70 wt%. The nanocrystals were synthesized by wet chemical method. The detailed structural characterization was performed by means of X-ray diffraction and micro-Raman spectroscopy measurements. The results of systematic measurements of magnetic AC susceptibility as a function of temperature and frequency are presented. We observed different types of magnetic behavior. For ZnO samples doped with low content of Fe_2O_3, the results of low-field AC susceptibility are satisfactorily explained by superparamagnetic model including inter-particle interactions. With the increase of magnetic Fe_2O_3 content, the spin-glass-like behavior is observed.
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Content available remote Raman Scattering from ZnO(Fe) Nanoparticles
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EN
Nanocrystalline samples of ZnO(Fe) were synthesized by wet chemical method. Samples were characterized by X-ray diffraction to determine composition of the samples (ZnO, Fe₂O₃, ZnFe₂O₄) and the mean crystalline size (8-52 nm). In this paper we report the experimental spectra of the Raman scattering (from 200 to 1600 cm¯¹). Main characteristics of experimental Raman spectrum in 200 to 1600 cm¯¹ spectral region are: sharp peak at 436 cm¯¹ and broad two-phonon structure at ≈ 1150 cm¯¹, typical of ZnO;broad structure below 700 cm¯¹ that has different position and shape in case of ZnFe₂O₄ or Fe₂O₃ nanoparticles.
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Content available remote Optical Properties of Plastically Deformed Copper
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EN
Pure copper (99.99), prepared in the sample of square cross-section (10 × 10 mm^{2}) and length about 50 mm, was extremely plastically deformed with the repeated application of Equal Channel Angular Pressing (ECAP). ECAP was applied as an effective technique for producing bulk nano-scaled structures. Optical properties of the sample were investigated using Raman spectroscopy. Two types of lines: narrow (with width of ≈ 7 cm^{-1}) and wide ( ≈ 40 cm^{-1}) are registered. Existence of two types of lines indicates that in the specimen exists nano-sized crystal structures of both Cu and CuO related with three dimensional amorphous boundary spaces, which indicates that plastic deformation of the sample did not lead to total amorphisation of the specimen.
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Content available remote Raman Spectroscopy of Multiphonon Emission Process in Ni-Doped PbTe
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In this paper, we present room temperature unpolarized Raman scattering spectra of Ni doped PbTe single crystal sample. Crystal of PbTe(Ni) was grown by the Bridgman method. The Ni concentration in the sample used here was 1× 10^{19} at./cm^{3}. Well resolved peaks appear at about 126, 143, 181, 362 and 724 cm^{-1}. The modes at 126 and 143 cm^{-1}, which are also observed in other telluride compounds, originate from vibrations in TeO_2. We assume that the mode at about 181 cm^{-1} is connected to excitations of a local phonon mode in the vicinity of an impurity atom (donor Ni^{3+} state). Modes at about 362 cm^{-1} and 724 cm^{-1} are the second and fourth harmonic of a local phonon mode, registered here due to multiphonon emission.
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