A determination of soil corrosivity on three sections of a main gas pipeline in the Western region of Ukraine has been carried out. We have distinguished areas of development of biocorrosive processes with the participation of sulphate-reducing bacteria (SRB). Soil evaluation by the degree of corrosivity has been conducted. We used weight, titrimetric, gravimetric methods, pH-metry, ten-fold limit dilution method and Postgate nutrient medium B for culturing SRB. It has been established that the soil in the first area selected along the lower generatrix of the main gas pipeline has a high degree of corrosivity. It was ascertained that corrosive metal damage increases in the “ferrozone” with the growth of metal exposition time from 24 to 72 hours. The soil selected in the middle part and from above the pipeline refers to soils with a normal degree of corrosive activity. Innovative biostable insulating coatings based on bituminous-polymerous mastic MBPID-1 have been developed, modified with organic inhibitors from the class of quaternary ammonium salts and amines. Regularities of influence of nature of nitrogen-containing corrosion inhibitors of industrial production M, N, L, H and K on the corrosion rate of 17G1S steel for 180 days have been established. It was found that the corrosion rate of steel specimens remained unchanged throughout the study in variants with the presence of inhibitors H and K in the test systems, which indicated their bioresistance to the effect of SRB bacteria.
The aspects of complex technology of sewage purification and utilization of purification sludge were investigated in the article. The authors substantiated the possibility of purifying sewage from heavy-metal ions by means of zeolite and utilizing sewage sludge in bricks production. The adsorption capacity of the zeolite from Sokyrnytsia deposit was studied for cupric and manganese ions in relation to its fractional composition. The comparative effectiveness studies of heavy metals adsorption by natural zeolite and anthracite were carried out. The optimal sorption parameters of these ions were selected based on the investigation results of their adsorption dynamics in the Cu2+ and Mn2+ solutions. The prospects of sewage sludge utilization by means of its thermal pyrolysis at the temperatures of 600-700°С were studied. The modifying additive was obtained, which can be added to the ceramic mixture and increase the porosity, reduce the density and decrease the thermal conductivity of course solid bricks.
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