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The utilisation of fine coal waste is still limited, even though its availability is very abundant in the mining industry. This study utilises fine coal by converting it into syngas through catalytic gasification. The gasification process was carried out at a temperature range of 350–550°C for 10–50 minutes using natural zeolite as a catalyst. The syngas composition and quality parameters were evaluated through the H2/CO ratio, heating value, and gasification efficiency. From the research results, fine coal contained high amounts of carbon and fixed carbon. Temperature is the variable that most influences the gasification process. The addition of zeolite actively increased the CO content in the syngas. The H2/CO ratio of syngas >1, the highest HHV and LHV 16.15 and 14.46 MJ/Nm3 with the highest carbon conversion efficiency value of 88.85%, made fine coal very suitable to be used as raw material for the gasification process to produce environmentally friendly syngas.
EN
The rapid progress of the CPO industry in Indonesia is not in line with good waste management and utilization. Palm empty fruit bunch, as the first waste from the CPO production process in Indonesia, is mostly piled on the ground. Palm empty fruit bunch must be processed to reduce pollution and increase its use-value. This study aimed to convert oil palm empty fruit bunches solid waste through the gasification process using Indonesia’s natural zeolite into synthesis gas. Gasification takes place at 350–550°C by added 12.5% wt zeolite using a modified updraft gasifier. Good results were achieved at 550°C with a gas composition of 22.64% vol CH4, 29.22% vol CO, and 3.4% vol H2. The gasification efficiency is evaluated through carbon conversion efficiency (CCE) and cold gas efficiency (CGE). Both the highest CCE and CGE were found at 550°C by 95.74% and 81.65% respectively. The results showed that the gasification temperature has the greatest influence in driving higher carbon conversion to syngas and palm empty fruit bunches are very suitable for conversion into environmentally friendly syngas in the CPO industry.
EN
Water pollution in rivers is still a crucial problem for the countries that use river water as the primary water source. This study aimed to determine the water quality of the Musi river and the content of heavy metals in water, sediment and mussels as well as to predict the water quality of the Musi river in the next five years. The water samples were taken from 18 stations (sampling points) from upstream to downstream to be checked physically, chemically and biologically. Prediction of the river water quality was made using the QUAL2Kw software. The research results show that the Musi River water is categorized as lightly polluted with concentrations of TSS and DO that have passed the threshold. The heavy metals in river water, such as Pb and Cr have also passed the quality standard. The Fe, Mn, and Zn concentrations are pretty high in the sediment. In turn, in mussels, the metals measured were Fe, Cu, and Zn. The prediction results reveal that several values of the river quality parameters will pass the threshold value with the same pattern tendency from each station.
EN
Modification of bentonite by the Al/Fe metal oxide pillarization process was carried out with metal oxides. The bentonite pillars were successfully characterized using an X-Ray Diffraction (XRD) spectrophotometer. The results of XRD characterization showed the peak diffraction angle (2θ) in metal-pillared bentonite was 26.84° at 698.98 cps. Meanwhile, in thermally and chemically activated bentonite, the peak angles were marked at 20.64° and 26.7°. There is a shift in the peak angle after activation and pillarization. XRD patterns showed dioctahedral smectite and quartz accessory minerals.
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