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Content available remote Radiation-induced paramagnetic centers in Bioglass(R).
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EN
The X-band (v=9.4 GHz) electron spin resonance (ESR) and thermally stimulated luminescence (TSL) spectra of the UV-, X-, and gamma -irradiated Bioglass(R) samples of different composition (Bioglass(R) I and Bioglass(R) II) have been investigated. The efficiency of generation of electron and hole centers strongly depends on basic Bioglass(R) composition and is almost independent of ionizing radiation type and presence of Fe/sup 3+/ non-controlled impurity in the glass network. The spin Hamiltonian parameters (g and a values) and thermal stability of the radiation-induced centers have been evaluated. The results of TSL measurements show good agreement with ESR data. The energetic structure, formation peculiarities and specific models of the radiation-induced paramagnetic centers in the Bioglass(R) network are discussed.
EN
Radiocarbon 14C is a cosmogenic isotope, which is most extensively used by scientists from a wide variety of fields. Its rate of generation in the atmosphere depends on solar modulation and thus, studying 14C concentration in natural archives, one can reconstruct solar activity level in the past. The paper shows results of box-model calculations of generation of the 14C isotope in the atmosphere and its relative abundance during the time interval 1389–1800 AD, taking into account influence of changing climate. This interval includes the deep minimum of solar activity and period of significant change in atmospheric concentration of CO2 and global temperature. The performed analysis showed that concentration of 14C in the atmosphere reflects not only variations of the galactic cosmic rays intensity but as well changes of temperature and atmospheric CO2 concentration. It is shown that the decrease in CO2 concentration in the atmosphere during 1550–1600 can be connected with absorption of CO2 by the ocean surface layer. Thus, taking into account the climatic changes is an important condition for the reconstruction of solar activity in the past using data based on cosmogenic isotopes.
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