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Improvement of Sorption Capacity and Applicability of Biosorbent by Immobilization

100%

Hroncova J. , Luptakova A. , Briancin J. , Kupka D.

tom Vol. 1, no. 1

645--651

The water contamination by toxic metal ions is a worldwide environmental problem. High concentrations are hazardous for all living organisms, causing many disorders and diseases and ecological damages to the surroundings. Biosorption is an innovative technology that employs inactive and dead biomass (bacteria, fungi, algae, biowaste) for the recovery of metals from aqueous solutions. Sulphate-reducing bacteria utilization is one of the options how to prepare applicable sorbent which removes metal ions from water. This material is created as a consequence of bacteria metabolism in anaerobic environment. The use of freely suspended biomass is often impractical and has some disadvantages. In contrast to this, application of immobilized biomass shows more benefits including increased mechanical strength, resistance to chemical environment, easy separation of cells and effluents, high biomass performance and repeated use in many adsorption/desorption cycles. Cell entrapment is the most widely used method for immobilization. In this technique, the cells are enclosed in a polymeric matrix which is porous enough to allow diffusion of substrate to the cells. The aim of this work was to examine and compare the sorption ability of biogenic iron sulphides created by sulphate-reducing bacteria in “free” and “entrapped” form. Precipitates were synthesized in reagent bottles with bacteria culture and growth media Postgate C, at 30 °C during 60 days, subsequently dried and analysed. Prepared samples were immobilized using sodium alginate. Sorption of cadmium from model solutions was realized in 100 ml Erlenmeyer flasks, with sorbent dose 1 g/l, during 24 hours. During experiments, the samples showed a satisfying stability and maximum adsorption capacity achieved 38 mg/g. The results refer to good sorption properties of immobilized samples and their potential for further practical use.

The Influence of Dielectric Properties on Heating of Sulphide Ores in Electromagnetic Field

88%

Znamenackova I. , Dolinska S. , Lacik J. , Hredzak S. , Briancin J.

tom Vol. 1, no. 1

43--49

Microwave heating is a form of high-frequency electromagnetic radiation. The heating of primary and secondary mineral raw materials in the microwave field depends primarily on their dielectric and thermal properties. The condition is the absorption of microwave radiation. Dielectric heating of materials occurs immediately after placing them in an electric high-frequency field. Knowledge of the dielectric characteristics of mineral raw materials is an important assumption for the use of electromagnetic radiation at the intensification of technological treatment methods. Most mined minerals consist of several mineral components that have different dielectric properties. Most sulphides are well heated in a microwave field. Conversely, tailings components of ores, such as quartz, are transmission materials. The study of dielectric properties involves measurements of the complex relative permittivity ε*, which consists of a real and an imaginary part. The imaginary part of permittivity “loss factor” represents the measure of dielectric losses in the material. Microwave heating of sulphide ores and concentrates such are chalcopyrite, tetrahedrite, galena depends on their chemical composition and content of impurities. The article describes the influence of dielectric properties on heating of chalcopyrite in microwave field. SEM analyses of studied samples are presented.

Environmental Pollution Monitoring by Thin Metal Electrodes Prepared by Physical Vapor Deposition

75%

Briancin J. , Kolcunova I. , Dolnik B. , Kurimsky J. , Dzmura J. , Cimbala R. , Fabian M.

tom no. 1, vol. 2

13--16

This work is focused on environmental pollution monitoring utilizing thin metal electrodes on glassy/ceramic substrates prepared by physical vapour deposition. Besides others, it is well known that environmental pollution on electrical insulation is one of the problems faced by distribution utilities and electricity transmission system. Due to this reason there is a need to deal with monitoring of environmental pollution as it strongly influences their capability to withstand the high-voltage stress without the breakdown. It is the aim of present work to propose new system for environmental pollution monitoring based on application of extra-thin metal electrodes. The influence of morphology and chemical composition of pollutants on the surface resistance and conductivity of selected insulators is also discussed.

Artykuł dotyczy monitorowania zanieczyszczenia środowiska za pomocą cienkich elektrod metalowych na szklanych/ceramicznych podłożach przygotowanych przez fizyczne osadzanie z fazy gazowej. Widomym jest, że zanieczyszczenie środowiska odpadami izolacji elektrycznej jest jednym z problemów, przed którymi stoją firmy dystrybucyjne i system przesyłu energii elektrycznej. Z tego powodu istnieje potrzeba monitorowania zanieczyszczenia środowiska, ponieważ ma to duży wpływ niezawodność sieci wysokiego napięcia i jej awaryjność. Celem przedstawionych prac jest zaproponowanie nowego systemu monitorowania zanieczyszczenia środowiska w oparciu o zastosowanie bardzo cienkich elektrod metalowych. Omówiono także wpływ morfologii i składu chemicznego zanieczyszczeń na rezystancję powierzchniową i przewodnictwo wybranych izolatorów.