Wyniki wyszukiwania - Biblioteka Nauki

Nowa wersja platformy, zawierająca wyłącznie zasoby pełnotekstowe, jest już dostępna.
Przejdź na https://bibliotekanauki.pl

Ograniczanie wyników

2 Archives of Civil and Mechanical Engineering

Znaleziono wyników: 2

Liczba wyników na stronie

Wyniki wyszukiwania

Sortuj według:

Ogranicz wyniki do:

Kinetics of copper leaching from direct‑to‑blister copper flash smelting slag by sulfuric acid

100%

Gargul K. , Boryczko B. , Handzlik P. , Noga P. , Palimąka P.

tom Vol. 23, no. 1

art. no. e29, 2023

Coppermaking from sulfide concentrates entails two major steps: smelting and converting. In continuous direct-to-copper smelting process these two steps are combined into one. The principal advantages of this process are: isolation of SO2 emission to a single, continuous, SO2-rich gas stream, minimization of energy consumption and minimization of capital and operating costs. Disadvantages of the process are that about 25% of the Cu entering a direct-to-copper smelting furnace ends up dissolved in the slag (when compared with < 10% in traditional Peirce-Smith converting) and the cost of recovering this Cu is significant. Decopperization process is based on the reduction of cuprous oxide and other metals, mainly lead and iron, in the liquid state in an electric furnace in the presence of coke and technological additives. This paper presents the results of laboratory tests on flash smelting slag leaching with sulfuric acid solutions. Hydrometallurgical treatment of the slag could be an alternative route to the presently used way of processing. The influence of a number of leaching parameters such as sulfuric acid concentration, amount of H2O2 added, liquid to solid phase (l/s) parameter and process temperature on the copper leaching efficiency was investigated. Under optimized process conditions, 95.6% of the copper contained in the original sample of slag was transferred into a solution. The experimental results obtained in the study were supplemented with the analysis of the kinetics of the copper leaching process from the flash smelting slag. The commonly known from the literature diffusion model and chemical reaction model were used. The activation energy of copper leaching from flash smelting slag was estimated in the range from 12.77 to 17.34 kJ/mol.

Properties of new-generation hybrid layers combining hardfacing and nitriding dedicated to improvement in forging tools’ durability

86%

Kaszuba M. , Widomski P. , Białucki P. , Lange A. , Boryczko B. , Walczak M.

2020

tom Vol. 20, no. 3

212--223

This article deals with the subject of layers produced in a hybrid process combining hardfacing and nitriding. These layers are characterized by improved resistance to wear, which arises from the synergy between favorable materials during hardfacing and nitriding treatment. Tests were conducted on hot-work tool steel (H11) samples. Hardfaced layers consisting of three layers were applied to these samples, where layers were made from two materials-Robotool 46 and Hardface VMolc powder wires. Next, samples of both materials were nitrided using ZeroFlow gas nitriding technology, with control of potential aimed at obtaining a diffusion layer without a white zone of nitrides on the surface. The next step was to investigate the properties of hardfaced layers and of layers hardfaced after nitriding treatment. Conducted tests covered observations of the microstructure, microhardness measurements as a function of distance from the surface, measurement of stresses in the surface layer by means of X-ray diffraction, and tribological tests. Obtained test results show that hybrid layers combining hardfacing and nitriding may be suitable for improving the lifetime of tools applied in hot forging processes.