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PAHs and organophosphorus substances in burnt landfill material as a potential source of water and soil pollution

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Rykała W. , Fabiańska M. , Dąbrowska D. , Nourani V.

Geological Quarterly

2023

tom Vol. 67, No. 4

art. no. 42

Illegal landfills pose a potential threat to the aquatic environment due, in part, to the unprotected subsoil beneath them. We describe the toxicity of soil samples and incinerated solid waste from two illegal landfills in Poland, and discuss the potential negative impact on groundwater. Fifty samples were taken, including 32 from an illegal landfill in Trzebinia (southern Poland), and analysed by GC-MS. The PAHs detected included naphthalene, fluorene, phenanthrene, anthracene, acenaphthene, acenaphthylene, fluoranthene, pyrene, benzo(c)phenanthrene, benzo(a)anthracene, chrysene, benzo(b+k)fluoranthene, benzo(a)fluoranthene, benzo(c)fluoranthene, benzo(a)pyrene, benzo(e)pyrene, perylene, indeno[1,2,3-cd]pyrene, benzo(ghi)perylene and dibenzo(a+h)anthracene. The organophosphates detected were tris-(2-chloroisopropyl) phosphate, trisphenyl phosphate, tri-cresyl phosphate, tri(butoxyethyl)phosphate and tris(2-chloroethyl) phosphate. PAHs at <50 ppm/g predominate in the samples, though samples with total PAHs ranging to >100 ppm/g were also identified in both study areas. Among the organic phosphate concentrations in the leachates, tris-(2-chloroisopropyl) phosphate was most frequently observed, with concentrations reaching ~0.7 µg/l. These compounds within burnt waste and soil can negatively impact the safety of groundwater. Constant monitoring and research is needed to assess the negative effects of waste fires on unsealed ground beneath, and to help prevent further instances.

On the detection and attribution of streamflow persistence of rivers in Peninsular India

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Adarsh S. , Nourani V. , Johnson A. , Jayan A. , Archana D. S. , Amrutha A. J.

Acta Geophysica

2022

tom Vol. 70, no 3

1373--1383

Persistence expressed by hurst exponent (H) is estimated for streamflow of 122 stations in the basins of Peninsular India by three methods at different aggregation scales (daily, monthly mean, monthly and annual maximum). Mean H values indicated long term persistence (LTP) and the data of more than 70% stations showed LTP for other temporal resolutions. H displayed negative correlation with time series length, mean annual and specific mean discharges, while no significant correlation with catchment area. Positive dependence was found between persistence of streamflow and different climatic attributes (rainfall; maximum, mean and minimum temperature) for daily and annual maximum datasets.