The contribution summarises the results of oxygen activity determinations, which were measured and registered continuously in castings from cast irons with various types of graphite. The results were used to find the relationship between two variables: natural logarithm of oxygen activities and reverse value of thermodynamic temperature 1 /T. Obtained regression lines were used to calculate oxygen activity at different temperatures, to calculate Gibbs free energy \deltaG at the different temperatures and to calculate the single \deltaG value for significant temperature of the graphite solidification. The results were processed by a statistical analysis of data files for the different types of graphite with flake, vermicular and spheroidal graphite. Each material has its proper typical oxygen activities range and individual temperature function of Gibbs free energy for analysing and governing casting quality.
Metallic foams are materials that are subject of an ongoing research with the broad applicability in many different areas (e.g. automotive industry, building industry, medicine, etc.). These metal materials contain in their structure artificially created pores. These pores give them specific properties, such as: large rigidity at low density, high thermal conductivity, capability to absorb energy, etc. Since the discovery of porous metallic materials numerous methods of production have been developed. The aim of the paper is to introduce effective casting methods of manufacturing of metallic foams, namely cast metal filters from the aluminum alloy. Research deals with investment casting with use of pattern made of polymeric foam, which is used for production of metallic foam with open pores. The main disadvantage of this procedure consists in removing the mould material without damaging the fine structure of the cast filter. Plaster is used as the mould material and the most important result of this paper is the presentation of the effective procedure of plaster removal from the porous structure of cast filters.
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Piany metalowe są przedmiotem wielu badań gdyż znajdują szerokie zastosowanie w wielu dziedzinach np. produkcji samochodów. budownictwie czy w medycynie. W swojej strukturze zawierają sztucznie wytworzone pory, zapewniające uzyskanie specyficznych właściwości jak duża wytrzymałość, niewielka gęstość, wysokie przewodnictwo cieplne zdolność do absorpcji energii itp. Od czasu wynalezienia porowatych materiałów metalowych opracowano wiele metod ich wytwarzania. Celem opracowania jest wprowadzenie efektywnych metod odlewniczych produkcji pian metalowych, szczególnie ze stopów glinu. Studium zajmuje się precyzyjną metodą odlewania przy zastosowaniu modelu wykonanego z piany polimerowej stosowanej w produkcji piany z otwartymi porami. Główna niedogodność metody polega na trudności usuwania materiału formierskiego, bez naruszenia delikatnej struktury odlewanego filtra. Jako materiał formierski stosuje się gips i najważniejszym wynikiem pracy jest przedstawienie efektywnej procedury usuwania gipsu z porowatej struktury odlanego filtra.
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Purpose: The study concerns the formation of pinholes in castings formed by reaction between a green foundry mould and lamellar graphite cast iron. Great numbers of works have been aimed at clarifying the causes of pinholes formation in iron castings. In spite of this there exists no united opinion on the pinholes formation (genesis) and the authors of this contribution having studied this phenomenon in compacted graphite and spheroidal graphite iron castings were also aimed at lamellar graphite cast iron and they applied for it their knowledge gained in study of reoxidation processes during casting of ferrous alloys. Methodology: Experiments were done on castings of stepped bars moulded in green bentonite mixtures with s graduated moisture and with use of two types of carbonaceous matters. Metal was melted in a 100 kg induction furnace from the same charge. Inoculation was done in a ladle after pouring out from the furnace. Aluminium was dosed in the ladle in some cases and the inoculator kind was changed too. Results: Pinholes were present on castings as small flat pits; on horizontal surfaces sooner singly, on casting edges in clusters. The formation of pinholes wasn't caused by high moisture of moulds but the defect was sensitive to aluminium content in metal. In castings with high aluminium content > 0.01 % the pinholes were present in great numbers, and namely both under low, and also high moistures of moulding mixtures. In melts with low content of Al < 0.01 % the pinholes occurred less extensively only. Practical implications: Conclusions from literature about influence of Al on pinholes occurrence were confirmed in such a way. Study of the defect morphology has shown that the question is a oxidation reaction type of pinholes caused by oxidation of the residual melt between dendrites with formation of CO.
The powerful tool for defect analysis is an expert system. It is a computer programme based on the knowledge of experts for solving the quality of castings. We present the expert system developed in the VSB-Technical University of Ostrava called ‘ESWOD’. The ESWOD programme consists of three separate modules: identification, diagnosis /causes and prevention/ remedy. The identification of casting defects in the actual form of the system is based on their visual aspect.
The last decade has seen growing interest in professional public about applications of porous metallic materials. Porous metals represent a new type of materials with low densities, large specific surface, and novel physical and mechanical properties, characterized by low density and large specific surface. They are very suitable for specific applications due to good combination of physical and mechanical properties such as high specific strength and high energy absorption capability. Since the discovery of metal foams have been developed many methods and techniques of production in liquid, solid and gas phases. Condition for the use of metal foams - advanced materials with unique usability features, are inexpensive ways to manage their production. Mastering of production of metallic foams with defined structure and properties using gravity casting into sand or metallic foundry moulds will contribute to an expansion of the assortment produced in foundries by completely new type of material, which has unique service properties thanks to its structure, and which fulfils the current demanding ecological requirements. The aim of research conducted at the department of metallurgy and foundry of VSB-Technical University Ostrava is to verify the possibilities of production of metallic foams by conventional foundry processes, to study the process conditions and physical and mechanical properties of metal foam produced. Two procedures are used to create porous metal structures: Infiltration of liquid metal into the mold cavity filled with precursors or preforms and two stage investment casting.