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1 Bulletin of the Polish Academy of Sciences. Technical Sciences

1 2013

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Investigations of polycaprolactone/gelatin blends in terms of their miscibility

100%

Kolbuk D. , Sajkiewicz P. , Denis P. , Choinska E.

tom Vol. 61, nr 3

629--632

Synthetic and natural polymers blends represent a new brand of materials with application in wound healing, scaffolds or drug delivery systems. Polycaprolactone/gelatin (PCL/Gt) blends were analyzed in terms of their miscibility. The PCL structure was investigated as a function of Gt content. Changes in the PCL spherulitic structure with Gt content were investigated by a polarizing-interference microscope. The analysis of the glass transition temperature (Tg) of both components as a function of PCL/Gt ratio by differential scanning calorimetry indicates that the system of polycaprolactone/gelatin belongs to a type of s.c. compatible system, being intermediate between miscible and immiscible systems. There is possibility of very limited miscibility of both components. Supplementary wide angle X-ray scattering results are presented.