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Content available remote The role of mineral phases in the biogas production technology
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EN
In the field of electric power industry, renewable energy sources, fertilisers, reclamation, and waste management, biomass is widely studied and used. Minerals are present in every step of biogas transformation, but their forms, occurrence, and composition have not been studied yet. However, there is no comprehensive study research that would address the presence of mineral phases in the process of biogas production. This aim of the study is determination of the amount and composition of the mineral phases present in fermentation residues resulting from different production technologies. Digestate mineral composition was analysed using 46 samples from agricultural biogas plants and university testing biogas reactor. The majority of samples contained the amorphous phase. Minority phases consisted of quartz, albite, orthoclase, muscovite, and amphibole. Opal-CT was found in eleven samples (1.26 to 12.1% wt.). The elements present in gas-liquid fluids or in liquids, gases and aerosols within the biogas technology system may create mineral phases, namely the amorphous phase or the crystalline phase under certain conditions. Opal-CT may enter the fermenter as part of plant tissues referred to as phytoliths, or as an unwanted admixture of different origin. It may also originate from the present amorphous SiO2.
EN
The only previous U-Pb zircon date for the the Early Carboniferous flysch sequence of the Moravo-Silesian Paleozoic Basin was published in 1987 from tuffogenic material from Kobylí Quarry at Krásné Loučky near the town of Krnov (Silesia, Czech Republic). The measured age of 319 Ma did not agree with its stratigraphic position, and was used as the basis for a hypothesized block of Late Carboniferous paralic molasse incorporated during a later tectonic event. During a survey of the still active quarry in 2010, volcaniclastic horizons were identified and sampled. Direct correspondence of the tuff units to those sampled in 1987 cannot be proved but is likely. High precision chemical abrasion - thermal ionization mass spectrometry (CA-TIMS) U-Pb dating of zircon from this new material has yielded an age of 340.05 ± 0.22 Ma, which correlates to the previously inferred stratigraphic age of the locality and the current calibration of the Early Carboniferous geologic time scale. The newly established age corresponds to the Visean stage and dates the boundary between the Horní Benešov and Moravice formations that can be correlated with other foredeep basins of the Culm in the European Variscides. A population of detrital Cambro-Ordovician zircons and a single 2.0 Ga old zircon crystal from the same volcaniclastic layer dated by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) are consistent with the known age of source material in the Variscan orogenic front.
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