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The presence of microplastic pollution in coastal areas has garnered attention due to its detrimental impact on aquatic ecosystems and human health. In this study, our objective was to identify and characterize microplastics in the Banger River area of Pekalongan City, which is known for its numerous industrial activities, particularly batik small-medium industries. The extraction process involved filtration, drying, wet peroxide oxidation, density separation using NaI, and identification of microplastic particles. The shape, color, and size of the particles were characterized using a stereo microscope, while Fourier Transform Infra-Red Spectrometer and the hot needle method were employed for chemical structure analysis. Given that rivers serve as primary conduits for waste transport from land to sea, we conducted sampling at different times of the day. Our findings revealed an average of 0.61 ± 0.47 particles/m3 in the morning, 0.59 ± 0.67 particles/m3 in the afternoon, and 0.10 ± 0.02 particles/m3 in the evening. Among the microplastic polymers analyzed, we successfully identified polypropylene as one of the two predominant types. To establish a baseline for mitigating the release of plastic waste and microplastic residues into the environment, long-term monitoring is essential to evaluate the flow of plastic waste and microplastics from Indonesian rivers to the oceans.
EN
This research explores the viability of converting discarded Polyethylene Terephthalate (PET) plastic waste into a valuable resource through the implementation of pyrolysis and refuse-derived fuel (RDF) technologies. The objective is to assess the potential of PET charcoal waste as an efficient source for RDF generation, surpassing the energy recovery and recycling potential of PET waste. The study introduces three RDF variants: RDF PET100, RDF PET50, and RDF PET0. RDF PET100 is comprised entirely of PET charcoal, RDF PET50 combines 50% PET charcoal with 50% wood debris, and RDF PET0 consists entirely of wood debris. Comprehensive assessments of water content, ash content, and calorific value were conducted to evaluate the quality of these RDF formulations. Results indicate that RDF PET100 exhibits a water content of 2.63%, ash content of 0.73%, and calorific value of 5,976 MJ/kg. Similarly, RDF PET50 showcases a water content of 3.6%, ash content of 1.05%, and calorific value of 5,587 MJ/kg. RDF PET0 presents a water content of 7.51%, ash content of 1.36%, and calorific value of 4,198 MJ/kg. The outcomes underline the potential of PET plastic waste repurposing through RDF and pyrolysis techniques. Particularly, RDF PET100 emerges as a high-caliber fuel option characterized by its minimal water and ash content, coupled with a substantial calorific value. This innovation holds promise in mitigating plastic waste challenges, particularly pertinent in the context of Indonesia.
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