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EN
The effect of the wave-induced Stokes drift is not taken into account in traditional ocean circulation models used for SST simulations. The spectral parameterization scheme is considered to be the most accurate of the wave-induced Stokes drift calculation schemes. The numerical simulation results of sea surface temperature (SST) with the Stokes drift and SST without the Stokes drift in the North Pacific in 2014 were analyzed. The Stokes drift plays a cooling role in the North Pacific, and the most affected areas are high-latitude sea areas. The following factors are responsible for cooling: the seawater divergence caused by Stokes transport, changes in the sea surface current field caused by the Coriolis-Stokes force and the effects of turbulence caused by Langmuir circulation. The simulation of the vertical temperature profile in the mixed layer is improved when the Stokes drift is accounted for. The simulated results of SST using the Stokes drift approximate parameterization schemes and the spectral parameterization scheme are compared. The results confirm that the spectral parameterization scheme can be used for accurate SST simulation, and the Phillips spectrum approximate parameterization scheme is the best among the approximate parameterization schemes.
EN
Polyethylene glycol polynitrates may be used as plasticizers in propellants. In this study, ten derivatives of ethylene glycol dinitrate were investigated using the density functional theory method. The fitted densities (ρ’exp.) were obtained and were very close to the experimental values. The detonation properties were predicted using the modified Kamlet-Jacobs equations and the specific impulse (Is) was evaluated according to the largest exothermic principle. A new indicator, K = Is · ρ’exp., is proposed to evaluate the energetic characteristics of the plasticizers. Thermal stability is discussed by calculating the bond dissociation energies or energy barriers. The O−NO2 bond is the trigger bond for all of the compounds studied. Considering the energetic properties and stability, diethylene glycol tetranitrate, triethylene glycol hexanitrate, tetraethylene glycol octanitrate, pentaethylene glycol decanitrate and hexaethylene glycol dodecanitrate are potential energetic plasticizers for solid propellants. The influences of the −O−CH2−CH2− and −O−CH(ONO2)−CH(ONO2)− groups are also discussed, which will be helpful for the design of new highly energetic plasticizers by modifying the structures as required.
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