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Sulphate and arsenate minerals as environmental indicators in the weathering zones of selected ore deposits, Western Sudetes, Poland

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Parafiniuk J. , Siuda R. , Borkowski A.

2016

tom Vol. 66, no. 3

493--508

The results of a complex investigation of the sulphate and arsenate assemblages forming in the weathering zone of selected ore deposits in the Sudetes are presented. The development of the weathering zone has been characterised in the polymetallic ore deposits at Miedzianka–Ciechanowice and Radzimowice, and the pyrite deposit at Wieściszowice, which differ in the chemical compositions of the ore and barren minerals and the hydrological conditions. Secondary sulphate and arsenate mineral assemblages vary significantly among the ore deposits under study. Their crystallization is discussed, taking into consideration the stability of particular minerals and the paths of their transformation. It is shown that these minerals have great potential as indicators of weathering processes. A significant role for microorganisms in the formation of the weathering zone of the ore deposits under study is also proven.

Antropogeniczne przeobrażenia oerodowiska geochemicznego aluwiów Zagożdżonki [Puszcza Kozienicka]

100%

Lis J. , Parafiniuk J. , Pasieczna A.

tom Vol. 55, nr 1

79-79

The paper presents detailed geochemical survey of stream sediments in Zagożdżonka river system. The Zagożdżonka river drains agricultural areas and forests [Puszcza Kozienicka] and flows through towns-Pionki and Kozienice. The works [metallurgical, power plants, plastic materials, munitions-factory localized in towns put industrial and communal sewage into Zagożdżonka river. Active sediments (180 samples; <0.2 mm) were leached with HCl (1:4); then, using the ICP-AES method determinations were made the concentration of Ag, Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, P, Pb, S, Sr, Ti, V and Zn. Mercury concentration was measured using the CV-AAS method. The geochemical survey reveals that industrial plants activity are the main sources of anthropogenic pollution of stream sediments in Zagożdżonka river catchment. The strong local anomalies of As, Be, Ca, Cd, Cr, Cu, Hg, Ni, Pb, Sr, Ti and Zn near Pionki and Kozienice towns can be related to low efficiency of sewage treatment plants in metal removing.