X-ray powder diffraction (XRD) is an established tool for the investigation of energetic materials. Whereas positions and intensities of diffraction peaks yield information on the crystal structure, peak profles are related to the real structure described by crystallite size, shape and microstrain. A series of energetic materials were measured at the synchrotron ANKA, and the size/strain broadening of FOX-7, RDX and ADN is discussed in relation to crystal structures and properties.
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