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EN
The objective of this study was to compare the efficacy of human chorionic gonadotropin (hCG) for the stimulation of ovulation within 48 h after treatment in mares, which had a ≥35 mm follicle. A total of 41 oestrus cycles of 21 mares (9 Thoroughbred, 6 Dutch Warmblood, and 6 Friesian), between 7 and 12 years of age were used for this study. All the mares were intramuscularly treated with Hcg, at the dose of 3 000 IU when a follicle ≥35 mm was detected. They were examined daily by transrectal ultrasonography, until the ovulation was confirmed. It was found that the diameter of follicle before ovulation was more significant, and oestrus duration was longer in Friesian mares than those of Thoroughbred and Dutch Warmblood ones. Moreover, the percentage of mares ovulating within 48 h after hCG treatment was significantly lower in Friesian mares, when compared to that of the other breed mares. There was no significant difference in these parameters between Thoroughbred and Dutch Warmblood mares. In conclusion, the efficacy of hCG may be different among mares of different breeds. The percentage of ovulation within 48 h after hCG treatment was lower in Friesian mares when compared to the other breeds. Therefore, various strategies are needed for the stimulation of ovulation in Friesian mares.
EN
Poly(methyl methacrylate)-holmium orthovanadate (PMMA-HoVO4) nanocomposites were synthesized using emulsifierfree emulsion polymerization system in two ways. In the first one, the HoVO4 nanoparticle dispersion was added to the emulsion system before or after polymerization start (in situ polymerization). In the other one, nanoparticle dispersion and polymeric latex were mixed together at room temperature (blending). Crystalline HoVO4 nanoparticles (about 60 nm) were synthesized by coprecipitation method. Three different composite latexes were synthesized by varying the potassium persulfate concentration and the time of HoVO4 nanoparticles addition. According to the dynamic light scattering analysis, the size of the polymer beads in the latexes is between 244.8 nm and 502.5 nm and the PDI values are in the range of 0.005 to 0.206. Infrared spectral analysis showed that HoVO4 caused some changes in the structure of the polymer. Luminescence measurements attempted to determine optical properties of the nanocomposites. The results have shown that HoVO4 nanoparticles do not protect their structure due to the reaction with persulfate radicals but that they enter the polymer beads and change the luminescence properties of the polymer forming a new material with different properties.
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