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1
Content available remote Doping and Characterization of Wide-Gap II-VI Epilayers
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In this paper we review the properties of n-type doped ZnSe and CdTe epilayers grown by molecular beam epitaxy on (100) GaAs substrates. Recent results of photoluminescence, transport measurements, secondary ion mass spectroscopy and deep-level transient spectroscopy are discussed. A major emphasis is placed on the effect of different dopant species and the role of the deviation from stoichiometry on the doped epitaxial layers. Since deep defect states play an important role in determining the properties of the doped materials, considerable attention is directed towards characterization and identification of deep-lying defect states, both native and introduced by dopants. In particular, in the case of ZnSe the deep-level transient spectroscopy results clarify why Cl is superior to Ga as an effective n-type dopant. They provide strong evidence that chlorine - unlike Ga - does not introduce by itself any detectable deep defects into the ZnSe lattice. In the case of CdTe, we focus on the influence of the deviation from stoichiometric growth conditions in the molecular beam epitaxy process and on the properties of In doped layers. We discuss resistivity, Mn diffusivity and the presence of various deep defects in layers grown at different Cd/Te flux ratios.
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Content available remote Graded Quantum Well Structures Made of Diluted Magnetic Semiconductors
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In this paper we review results of studies of two types of spatially graded quantum well structures containing various layers of diluted magnetic semiconductors Cd_{1-x}Mn_{x}Te or Cd_{1-x-y}Mn_{x}Mg_{y}Te. The design of the structures has been recently proposed by us and suitable samples have been grown by a modified molecular beam epitaxy method. In the structures of the first type a digital profiling of the composition of the constituent material in the growth direction allowed to produce quantum wells with a specifically required shape of the confining potential (including parabolic, half-parabolic, triangular, and trapezoidal). Such samples were used for (i) determination of the conduction and valence band offsets in MnTe/CdTe and MgTe/CdTe systems, (ii) for the demonstration of an enhanced exciton binding in a parabolic confining potential as well as for (iii) demonstration of the possibility of "spin-splitting engineering" in diluted magnetic semiconductors quantum structures. In the second type of the structures, a precise in-plane profiling of either quantum well width or the barrier width or n-type doping intensity was realized. These structures were subsequently used for studies of the evolution of optical spectra with an increase in the concentration of confined two-dimensional gas of conduction electrons.
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We present an attempt to control the properties of CdTe/ZnTe self-assembled quantum dots during their formation in the process of molecular beam epitaxy. Namely, the structures were in situ annealed at various temperatures and annealing times after the formation of quantum dots, before the deposition of a capping layer. Depending on the annealing parameters, the dots exhibit different optical properties which were studied by means of spatially resolved photoluminescence. From the analysis of these results, the information about relative changes of the average size and sheet density of quantum dots was extracted.
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Content available remote Electrical Properties of p-ZnTe/n-CdTe Photodiodes
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Current-voltage (I-V) and capacitance-voltage (C-V) characteristics of photovoltaic, thinfilm p-ZnTe/n-CdTe heterojunctions have been studied in the temperature range of 280-400 K. The p-n junctions were grown by MBE on (100) semi-insulating GaAs substrates. From the analysis of I-V and C-V curves the potential barrier height of the junctions and its temperature dependence are determined. The relatively large value of the temperature coefficient of the potential barrier height (2.5-3.0 × 10^{-3} eV/K) indicates a high density of defects at the p-ZnTe/n-CdTe interface. The presence of interface defects limits the efficiency of the solar energy conversion of these devices.
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The first direct measurement of the magnetization of donor bound magnetic polarons in diluted magnetic semiconductors is reported. The experiment has been performed taking advantage of photomemory effect found in n-type Cd_{1-x}Mn_{x}Te_{1-y}Se_{y} crystals doped with In. Good agreement between experimental results and theory of bound magnetic polarons is observed.
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Stimulated emission by optical excitation has been investigated in CdZnTe/CdMnTe quantum well heterostructures. Laser action has been achieved at 4.2 K and at 77 K with relatively low threshold values of the excitation intensity. Photοluminescence excitation spectra of the stimulated emission were obtained indicating that the optical gain involves exciton-exci­ton inelastic scattering.
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In this work, we observed effects of changing the electron concentration and electron mobility upon the poling of the Cd_{0.96}Zn_{0.04}Te ferroelectric gate deposited on the top of the CdTe-based modulation doped quantum well structure, which are confirmation of the existence of the electrostatic field originating from the ferroelectric material, which can be controlled by an external voltage. The analysis of the data obtained from the Hall effect measurements showed that the electron mobility and carrier concentration decreased by a factor of 2.5 and 1.5, respectively upon the negative poling of the gate with respect to the poled by the positive voltage. Moreover, the electrostatic field, depending on its directions, causes depletion of accumulation of electrons in the 2D channel, i.e., it is a source of the field effect.
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Content available remote Search for T-Shaped Quantum Wires in CdTe/CdMg(Mn)Te System
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We attempted to produce and to investigate T-shaped wire structures of II-VI compounds. Our samples were grown on GaAs hybrid substrates in a two-stage growth process. The photoluminescence measurements resulted into two different possible polarization behaviors of recorder signal. We interpret one of these behaviors as due to quantum wire formation.
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Content available remote Epitaxial Growths of II-VI Compounds on (110) Substrates
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We studied epitaxial growth conditions of II-VI semiconductors on (110) substrates, which is indispensable for fabrication of T-shaped quantum wire structures. We experimented with different types of (110)-oriented substrates and monitored the surface quality of deposited layers in situ by reflection high energy electron diffraction and ex situ by photoluminescence. The aim of this work is to find optimum growth conditions of II-VI compounds on a cleaved edge of a superlattice as required by the overgrowth method.
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Rare earth ions implanted GaN has been investigated by transmission electron microscopy versus the fluence, using Er, Eu or Tm ions at 150 keV or 300 keV and at room temperature. Point defect clusters and stacking faults are generated from low fluences (7×10^{13} at/cm^2), their density increases with the fluence up to the formation of a highly disordered layer at the surface. This highly disordered layer is observed from a threshold fluence of 3×10^{14} at/cm^2 at 150 keV and 3×10^{15} at/cm^2 at 300 keV, and appears to be composed of voids and misoriented nanocrystallites. Its thickness rapidly increases with the fluence, and then saturates. Both basal and prismatic stacking faults were observed. Basal stacking faults are I_1 in majority, but E or I_2 have also been identified. I_1 basal stacking faults propagate easily through GaN by folding from basal to prismatic planes. Channelling implantation, increasing the implantation temperature from room temperature to 500ºC, or implanting through a 10 nm thick AlN cap reduce the crystallographic damage, particularly by retarding the formation of the highly disordered layer. Implanting through the AlN cap allows the highly disordered layer formation threshold fluence to be increased by one order of magnitude, as well as the annealing at high temperature (1300ºC) which brings about a strong optical activation of the rare earths.
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We report milikelvin studies of light induced metastable changes of the conductivity of the In doped Cd_{0.95}Mn_{0.05}Te_{0.97}Se_{0.03} crystals in the vicinity of the metal-insulator transition.
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Magnetophotoluminescence measurements at liquid helium temperatures were carried out on asymmetric double quantum wells based on CdTe/CdMgTe heterostructures. Due to doping with shallow iodine donors, a two-dimensional electron gas was present in the quantum wells. The samples studied differed with the quantum well widths and doping level. We show a resemblance of the luminescence to results obtained on single quantum wells which suggests that in samples studied the quantum wells are not strongly coupled.
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Room temperature photoreflectance spectroscopy was used to investigate CdTe/Cd_{1-x}Mn_{x}Te multiple quantum wells grown by MBE. Structures were indium δ-doped into the well or into the barrier. The value of heavy and light hole subbands splitting was measured and compared to the calculated ones. The influence of the position of δ-doping on the measured spectra was shown.
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Content available remote Deep Electron Traps in CdTe:In Films Grown by Molecular Beam Epitaxy
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N-type indium doped CdTe grown on n^{+}-GaAs by molecular beam epitaxy has been studied by the standard deep level transient spectroscopy and the isothermal Laplace-transform deep level transient spectroscopy. It was found that the Cd/Te flux ratio strongly influences the deep level transient spectroscopy results. The unusual temperature dependence of the electron emission rate in films grown at nearly stoichiometric conditions may point out that the observed defect is resonant with the conduction band.
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We present time-dependent reflectance spectra of wide (Cd,Mn)Te/(Cd,Mg)Te quantum wells. Interactions between excitons, trions, and carriers are studied for exciton densities up to 10^{11} cm^{-2}. The resonant excitation at different excitonic lines is analyzed.
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Content available remote Strain Relaxation of ZnTe/CdTe and CdTe/ZnTe heterostructures: In Situ Study
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The strain relaxation kinetics of ZnTe/CdTe and CdTe/ZnTe heterostructures grown on GaAs substrates by molecular beam epitaxy are studied by in situ reflection high-energy electron diffraction. The observed critical layer thickness is 5 monolayers for ZnTe/CdTe and less than 1 monolayer for CdTe/ZnTe. The relaxation is anisotropic. Dislocation core parameters and relaxation rate constants were determined using a kinetic model and assuming strain-dependent activation energy of dislocation movement.
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The first observation of electric dipole spin resonance of donor electrons in Cd_{1-x}Mn_{x}Te_{1-y}Se_{y} in far-infrared magnetotransmission is reported. Modification of the donor wave function due to non-diagonal exchange interaction with localized magnetic moments and to magnetic fluctuations are believed to allow this resonance. Hopping magnetoconductivity studied in the same crystals shows a behavior typical for wide gap diluted magnetic semiconductors.
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We review recent magneto-optical investigations performed on HgTe-CdTe semimetallic superlattices. Far infrared magnetotransmission data obtained as a function of temperature, photon energy, and sense of circular polarization are compared with the predictions of a comprehensive new theory which fully incorporates the complexities of type-III superlattice band structure. It is found that the theory accounts for nearly all of the many unusual features which have been observed experimentally. These include the occurrence of two cyclotron resonances due to holes; the coexistence of electron and hole cyclotron resonances in the low temperature limit; the observation of three distinct CRA minima; a step-like change in the temperature dependence of the electron cyclotron mass; and a dramatic increase of the CRI absorption peak intensity with increasing magnetic field.
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The spin resonance of excess electrons is observed with the detection either on the neutral or the negatively charged exciton X^{-} emission in type I CdTe/(Cd,Mg)Te quantum wells with excess electrons of low density. It is found that the electron spin-dependent and electron spin-conserving formation and recombination of X^{-} make the optical detection of the spin resonance of excess electrons feasible. For the first time, optically detected magnetic resonance is used to study fast optical transition processes in the nanosecond timescale where the microwave-induced magnetic transition rate is much lower than the optical transition rate.
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An influence of doping level on exciton properties in n-doped multiple quantum well structures of CdTe/CdMnTe is studied for multiple quantum well structures prepared in the way that donor (indium) concentration changes within the length of the sample. We show that the formation scenario for neutral donor bound excitons in low-dimensional structures can be different from that observed in bulk samples. We further show that in the case of such quantum well structures we can selectively excite either photoluminescence emission of localized or donor bound excitons, which is a consequence of surprisingly weak energy transfer link between two types of excitonic transitions.
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