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2 Physicochemical Problems of Mineral Processing

2 2023

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Quinic acid as a novel depressant for efficient flotation separation of scheelite from calcite

100%

Huang Z. , Kuang J. , Yu M. , Ding D.

tom Vol. 59, iss. 2

art. no. 166008

There are difficulties to the conventional depressant for achieving separation of scheelite from calcite for the sake of their similar surface properties. The paper reported that a new depressant quinic acid (QA) was used for separating scheelite from calcite. The adsorption experiments, zeta potential experiment, contact angle, FTIR, XPS analysis and crystal chemistry analysis were utilized to known the depression mechanism of selectivity. The results showed that the recovery of calcite decreased drastically after QA added, whereas hardly influenced on scheelite. The tungsten concentrate could reach 66.24% WO3 grade and 89.46% recovery with 1.5×10-4 mol•L-1 QA at pH=9. The surface adsorption quantity of the QA on calcite was much greater than scheelite, which enhanced significantly the hydrophilicity of calcite surface. Due to its negative charge, QA could be adsorbed on the surface of calcite which had positive charge instead of that of scheelite with negative charge. Subsequently, free carboxyl groups of QA could chelated with Ca2+ species on the calcite surface to form stable chemical adsorption in order to prevent the Pb-BHA to form further adsorption on that, so there was no increase significantly on hydrophobicity. However, QA was obviously weak for adsorbing while Pb-BHA which could still be chemically adsorbed on scheelite surface of pre-treated with QA.

Efficient solidification of Pb2+ by activated tungsten tailings and cement

75%

Cheng H. , Kuang J. , Zhu L. , Yuan W. , Huang Z. , Yang Y.

tom Vol. 59, iss. 2

art. no. 162618

The preparation of cementing admixture from tailings and co-solidification of Pb2+ with cement is a green way to realize the resource utilization of tailings and treatment of the lead-containing wastewater. In this paper, the tungsten tailings were activated in different ways, and the mechanical properties of the tungsten tailings-cement solidified body with different activation systems and the solidification behavior of Pb2+ were studied. The phase and microstructure of the hydrated product were characterized by XRD, FT-IR, SEM and EDS. The results showed that the curing effect of Pb2+ was obviously different of different activation systems, and the curing effect of the solidified body of the ternary composite activation system (TCAS) was the best, second only to the pure cement system (PCS). Different activation methods have a significant impact on the mechanical properties of the solidified body. With the increase of the Pb2+ content, the compressive strength of the solidified body gradually decreased, the Pb2+ leaching concentration gradually increased; with the extension of the curing age, the compressive strength gradually increased, and the Pb2+ leaching concentration gradually decreased. In particular, the compressive strength of the 28d solidified body was 31.43 MPa and the leaching concentration of Pb2+ was only 0.38 mg/L when the Pb2+ content was 5%. The phase, microstructure and EDS results of the hydration products showed that Pb2+ was mainly solidified in the C-S-H gel.