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EN
In this study, Amberite XAD-7HP was used as the solvent-impregnated resin to separate each REE from the standard solution, which was mixed with the REEs (e.g., La Eu, Tb, Y and Ba). About 100 ppm of each of the REEs was separated from DI water using extraction chromatography. REEs were separated by extraction chromatography using Amberite XAD-7HP resin, the changes in the pH values of the HCl and HClO4 were between 0.2 N and 5 N, and the extraction rate of the solution was between 0.5 and 3 ml/min. The La solution with the separated REEs was leached. The solid-state REEs were annealed between 1083K. The extraction result was analyzed with ICP-AES and an X-ray diffractometer. Each REE was successfully separated with HCl and HClO4 with pH values between 0.1 N and 3 N and with extraction rate between 1.0 m/min and 3.0 m/min.
EN
TlBr single crystals grown using the vertical Bridgman-Stockbarger method were characterized for semiconductor based radiation detector applications. It has been shown that the vertical Bridgman-Stockbarger method is effective to grow high-quality single crystalline ingots of TlBr. The TlBr single crystalline sample, which was located 6 cm from the tip of the ingot, exhibited lower impurity concentration, higher crystalline quality, high enough bandgap (>2.7 eV), and higher resistivity (2.5 × 1011 Ω·cm) which enables using the fabricated samples from the middle part of the TlBr ingot for fabricating high performance semiconductor radiation detectors.
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