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The ITO thin films deposited by magnetron sputtering for solar cell applications

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Szindler M. , Szindler M. M. , Lukaszkowicz K. , Matus K. , Nosidlak N. , Jaglarz J. , Fijalkowski M. , Nuckowski P.

Bulletin of the Polish Academy of Sciences. Technical Sciences

2024

tom Vol. 72, nr 5

art. no. e150803

The paper presents the results of research on the surface topography and electrical properties of ITO thin films deposited by PVD for applications in silicon photovoltaic cells. The surface condition and chemical composition were characterized using a scanning electron microscope and the thickness and optical constants were measured using a spectroscopic ellipsometer. To compare the impact of the preparation process on the properties of layers, deposition was carried out at three different temperatures: 25, 200, and 400◦C. As the temperature increased, the surface roughness changed, which correlated with the results of structural tests. The crystallite size increased from 11 to 46 nm. This, in turn, reduced the surface resistance. The electrical properties were measured using a four-point probe method and then the prepared solar cells containing ITO thin films in their structure were examined. By controlling the deposition parameters, the surface resistance of the deposited layer (26 Ohm/✷) and the efficiency of the prepared solar cells (18.91%) were optimized. Currently, ITO has the best properties for use in optoelectronics and photovoltaics among the known TCO layers. The magnetron sputtering method is widely used in many industries. Therefore, the authors predict that TCO layers can replace currently used antireflection layers and reduce the number and dimensions of front metal contacts in solar cells.

How can hybrid materials enable a circular economy?

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Wacławek S. , Fijalkowski M. , Bardos P. , Kočí J. , Scholz S. , Hirsch P. , Domann G. , Černík M.

Ecological Chemistry and Engineering. S

2022

tom Vol. 29, nr 4

447--462

Climate change, critical material shortages and environmental degradation pose an existential threat to the entire world. Immediate action is needed to transform the global economy towards a more circular economy with less intensive use of fossil energy and limited resources and more use of recyclable materials. Recyclable materials and manufacturing techniques will play a critical role in this transformation. Substantial advancements will be needed to achieve a more intelligent materials design to enhance both functionality and enhanced sustainability. The development of hybrid materials combining functionality at macro and nano scales based on organic and inorganic compounds, that are entirely recyclable could be used for tremendous applications. In this mini-review, we provide the reader with recent innovations on hybrid materials for application in water, energy and raw materials sectors. The topic is very modern and after its deep study we propose a creation an international research centre, that would combine the development of hybrid materials with green manufacturing. We have highlighted a framework that would comprise critical themes of the initial research needed. Such a centre would promote sustainable production of materials through intelligent hybridisation and eco-efficient, digital manufacturing and enable a circular economy in the long term. Such activities are strongly supported by current environmental and economical initiatives, like the Green Deal, REPower EU and digital EU initiatives.