Chemical modification of TiO2 by H2PO 4 −/HPO 4 2− anions using the sol-gel route with controlled precipitation and hydrolysis: enhancing thermal stability

• Autorzy: Elghniji, K. , El, K. S. M. , Araissi, M. , Elaloui, E. , Moussaoui, Y.
• Języki publikacji: EN

Abstrakty

EN

Two titanium phosphate materials (TpP and ThP) have been successfully synthesized by sol-gel route with controlled precipitation and hydrolysis. The TpP material was obtained from the reaction between precipitated titania and phosphate buffer solution H2PO−4/HPO2−4(pH = 7.3). The ThP material was prepared through hydrolysis of titanium in the presence of H2PO−4/HPO24. The probable state of the phosphate anions in titania framework and their effect on the anatase-to-rutile transformation were characterized by ICP-AES, DTA-TG, 31P NMR, FT-IR, and Raman analysis HRTEM/SEM. FT-IR and 31P NMR analyses of titanium phosphate TpP calcined at low temperature showed that the phosphate species existed not only as Ti–O–P in the bulk TiO2 but also as amorphous titanium phosphates, including bidentate Ti(HPO4)2 and monodentate Ti(H2PO4)4. Increased calcination temperature only gave an enrichment of bidentate structure on the titania surface. For the ThP material, H2PO−4/HPO2−4anions were introduced into the initial solution, before precipitation, what promoted their lattice localization. At high temperatures, all the phosphorus inside the bulk of TiO2 migrated to the surface. The Raman analysis of both samples showed that the bidentate phosphates increased the temperature of the anatase-to-rutile phase transformation to more than 1000 °C with the formation of well crystalline TiP2O7 phase. This phenomenon was more evident for TpP sample.

Słowa kluczowe

EN

TiO2; phosphorus; crystal growth; bidentate; monodentate

• Czasopismo: Materials Science Poland
• Rocznik: 2014
• Tom: Vol. 32, No. 4
• Strony: 617--625
• Opis fizyczny: Bibliogr. 36 poz., rys., wykr.

Twórcy

autor

Elghniji, K.

• Materials, Environment and Energy Laboratory, (06/UR/12-01) Science Faculty of Gafsa, 2112, Gafsa, University of Gafsa, Tunisia,

autor

El, K. S. M.

• Materials, Environment and Energy Laboratory, (06/UR/12-01) Science Faculty of Gafsa, 2112, Gafsa, University of Gafsa, Tunisia

autor

Araissi, M.

• Materials, Environment and Energy Laboratory, (06/UR/12-01) Science Faculty of Gafsa, 2112, Gafsa, University of Gafsa, Tunisia

autor

Elaloui, E.

• Materials, Environment and Energy Laboratory, (06/UR/12-01) Science Faculty of Gafsa, 2112, Gafsa, University of Gafsa, Tunisia

autor

Moussaoui, Y.

• Materials, Environment and Energy Laboratory, (06/UR/12-01) Science Faculty of Gafsa, 2112, Gafsa, University of Gafsa, Tunisia
• Laboratory of Chemistry of Natural Substances, (UR11-ES74) Science Faculty of Sfax, 3018, Sfax, University of Sfax, Tunisia

Bibliografia

• [1] PADMANABHAN S.C., PILLAI S.C., COLREAVY J., BALAKRISHNAN S., MCCORMACK D.E., PEROVA T.S., GUNKO Y., HINDER S.J., KELLY J.M., Chem. Mater., 19 (2007), 4474.
• [2] BACSA R., KIWI J., OHNO T., ALBERS P., NADTOCHENKO V., J. Phys. Chem. B., 109 (2005), 5994.
• [3] COLON G., HIDALGO M.C., MUNUERA G., FERINO I., CUTRUFELLO M.G., NAVIO J.A., Appl. Catal. BEnviron., 63 (2006), 45.
• [4] REIDY D.J., HOLMES J.D., NAGLE C., MORRIS M.A., J. Mater. Chem., 15 (2005), 3494.
• [5] ZHANG J., LI M., FENG Z., CHEN J., LI C., J. Phys. Chem. B., 110 (2006), 927.
• [6] KOROSI L., OSZKO A., GALBACS G., RICHARDT A., ZOLLMER V., DEKANY I., Appl. Catal. B-Environ., 77 (2007), 175.
• [7] CHANG S., HOU C.Y., LO P.H., CHANG C.T., Appl. Catal. B-Environ., 90 (2009), 233.
• [8] ELGHNIJI K., HENTATI O., MLAIK N., MAHFOUDH A., KSIBI M., J. Environ. Sci., 24 (2012), 479.
• [9] YU J.C., ZHANG L., ZHENG Z., ZHAO J., Chem. Mater., 15 (2003), 2280.
• [10] YU J.C., HO W., YU J., YIP H., WONG P.K., ZHAO J., J. Environ. Sci. Technol., 39, 1175 (2005).
• [11] SHI Q., YANG D., JIANG Z., LI J., J. Mol. Catal. BEnzym., 43 (2006), 44.
• [12] COMSUP N., PANPRANOT J., PRASERTHDAM P., Catal. Comm., 11 (2010), 1238.
• [13] RAMADAN A.R., YACOUB N., AMIN H., RAGAI J., Colloid. Surf. A. Physicochem. Engin. Aspects., 352 (2009), 118.
• [14] GONG W., Int. J. Miner. Process., 63 (2001), 147.
• [15] KAZARINOV V.E., ANDREEV V.N., MAYOROV A.P., J. Electroanal. Chem. Interracial Electrochem., 130 (1981), 277.
• [16] XIA Y., JIANG Y., LI F., XIA M., XUE B., LI Y., App.Surf. Sci., 289 (2014), 306.
• [17] SAMANTARAY S.K., PARIDA K., J. Mol. Catal. AChem., 176 (2001), 151.
• [18] NAKAMOTO K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1986.
• [19] LIN L., LIN W., XIE J.L., ZHU Y.X., ZHAO B.Y., XIE Y.C., Appl. Catal. B-Environ., 75 (2007), 52.
• [20] PAWSEY S., MCCORMICK M., DEPAUL S., GRAF R., LEE Y.S., REVEN L., SPIESS H.W., J. Am. Chem. Soc., 125 (2003), 4147.
• [21] PARIDA K.M., ACHARYA M., SAMANTARAY S.K., MISHRA T., J. Colloid. Interface. Sci., 217 (1999), 388.
• [22] ELGHNIJI K., SORO J., ROSSIGNOL S., KSIBI M., J. Taiwan Inst. Chem. Eng., 43 (2012), 132.
• [23] KOROSI L., PAPP S., BERTOTI I., DEKANY I., Chem.Mater., 19 (2007), 4811.
• [24] YU H.F., YANG S.T., J. Alloy. Compd., 492 (2010), 695.
• [25] SHAO G.S., MA T.-Y., ZHANG X.J., REN T.Z., YUAN Z.Y., J. Mater. Sci., 44 (2009), 6754.
• [26] SHMUTZ C., BARBOUX P., RIBOT F., TAULELLE F., VERDAGUER M., FERNANDEZ-LORENZO C., J. NonCrys. Solids., 170 (1994), 250.
• [27] DJAFER L., AYRAL A., BOURY B., LAINE R.M., J. Colloid. Interface. Sci., 393 (2013) 335.
• [28] FAN X., TAO Y., YING W., JING Z., LING G., ZHAOSHENG L., JINHUA Y., ZHIGANG Z., Appl. Surf. Sci., 254 (2008), 5191.
• [29] KOVALCHUK T.V., SFIHI H., KORCHEV A.S., KOVALENKO A.S., IL’IN V.G., ZAITSEV V N., FRAISSARD J., J. Phys. Chem. B, 109 (2005), 13948.
• [30] DEL VAL S., LOPEZ GRANADOS M., FIERRO J. L.G., SANTAMARIA-GONZALEZ J., JIMENEZ LOPEZ A., BLASCO T., J. Catal., 204 (2001), 466.
• [31] WANG J., ZHU W., ZHANG Y., LI S., J. Phys. Chem. C, 111 (2007), 1010.
• [32] CHEN X., MAO S.S., Chem. Rev., 107 (2007), 2891.
• [33] SERRANO D.P., CALLEJA G., SANZ R., PIZARRO P., J. Mater. Chem., 17 (2007), 1178.
• [34] LV K., YU J., CUI L., CHEN S., LI M., J. Alloy. Compd., 509 (2011), 4557.
• [35] KELLY S., POLLAK F.H., TOMKIEWICZ M., J. Phys.Chem. B, 101 (1997), 2730.
• [36] LIU G., CHEN Z., DONG C., ZHAO Y., LI F., LU G.Q., CHENG H.M., J. Phys. Chem. B, 110 (2006), 20823

Identyfikatory

DOI

10.2478/s13536-014-0237-6