Warianty tytułu
Języki publikacji
Abstrakty
This work shows a paradoxical fact: a highly plasticized PVC sample containing the maximum amount of the plasticizer di(2-ethylhexyl) phthalate (DEHP) compared to medium- and low-plasticized polymers turned out to be the least toxic. This was confirmed in express bioassays for the pre-lethal reactions of Paramecium caudatum Ehrenber and Escherichia coli M-17 when determining the acute toxicity for mortality of Daphnia magna Straus and Ceriodaphnia affinis Lilljeborg, as well as in chronic tests for D. magna. The migration of DEHP from the tested PVC samples into water was confirmed by the mass spectrometry method. It was shown that the contact of PVC materials with hot water (70℃) led to a significant increase in the toxicity of the extracts compared to cold extraction (20℃). The search for safe composition of PVC materials must be carried out in the direction of the optimal ratio of PVC-polymer, plasticizer and heat stabilizer, as well as replacing the components of the composition with safe substances.
Rocznik
Tom
Strony
119--125
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
autor
- Vyatka State University, Moskovskaya Str. 36, Kirov, 610000, Kirov Region, Russia, morgan-abend@mail.ru
Bibliografia
- 1. Daiem M.M.A., Rivera-Utrilla, J., Ocampo-Perez, R., Mendez-Diaz, J.D., Sanchez-Polo, M. 2012. Environmental impact of phthalic acid esters and their removal from water and sediments by different technologies — A review. Journal of environmental management, 109, 164-178. DOI: 10.1016/j.jenvman.2012.05.014
- 2. Duarte N.D.A., de Lima L.E., Maraslis F.T., Kundi M., Nunes EA., Barcelos G.R.M. 2021. Acute Toxicity and DNA Instability Induced by Exposure to Low Doses of Triclosan and Phthalate DEHP, and Their Combinations, in vitro. Frontiers in genetics, 12, 649845. DOI: 10.3389/fgene.2021.649845
- 3. Environmental Regulatory Document PND F T 14.1:2:3:4.11-04. T.16.1:2:3:3.8-04. 2010. Method for determining the integrated toxicity of surface waters, including marine, ground, drinking, waste waters, water extracts from soils, waste, sewage sludge by changes in bacterial bioluminescence using the «Ecolum test-system». Moscow: Nera-S, 30 p.
- 4. Facciola A., Visalli G., Ciarello M.P., Di Pietro A. 2021. Newly Emerging Airborne Pollutants: Current Knowledge of Health Impact of Micro and Nanoplastics. International journal of environmental research and public health, 18(6), 2997. DOI: 10.3390/ijerph18062997
- 5. Federal Register FR 1.39.2007.03221. 2007. Methodology for determining the toxicity of water and water extracts from soils, sewage sludge, and waste by mortality and changes in fertility of ceriodaphnias. Moscow: Akvaros, 51 p.
- 6. Federal Register FR 1.39.2007.03222. 2007. Methodology for determining the toxicity of water and water extracts from soils, sewage sludge, and waste by mortality and changes in fertility of daphnias. Moscow: Akvaros, 51 p.
- 7. Federal Register FR 1.39.2015.19242. 2015. Environmental Regulatory Document PND F T 16.2:2.2- 98. Methodology for determining the toxicity of samples of natural, drinking, domestic and drinking, household waste, treated sewage, waste, thawed, technological water by the express method using the Biotester device. St. Petersburg: SPEKTR-M, 21 p.
- 8. Feng J.X., Zhao H.S., Gong X.Y., Xia M.C., Cai L.S., Yao H., Zhao X., Yan Z.H., Li Z.P., Nie H.G., Ma X.X., Zhang S.C. 2021. In Situ Identification and Spatial Mapping of Microplastic Standards in Paramecia by Secondary-Ion Mass Spectrometry Imaging. Analytical chemistry, 93(13), 5521-5528. DOI: 10.1021/acs.analchem.0c05383
- 9. Fernandes, M.C.S., Pereira, V.A., Fonseca, A.C., Ramalho, A., Coelho, J.F.J., Barros, R., Pereira, P., Pereira, J., Serra, A.C. 2021. Synthesis and characterization of biobased polyester PVC plasticizers to industrial manufacturing of tubes. Journal of applied polymer science, e50941. DOI: 10.1002/app.50941
- 10. Group E. 1996. Environmental fate and aquatic toxicology studies on phthalate esters. Environmental Health Perspectives, 65, 337.
- 11. Hahladakis J.N., Velis C.A., Webe R., Iacovidou, E., Purnell P. 2018. An overview of chemical additives present in plastics: Migration, release, fate and environmental impact during their use, disposal and recycling. Journal of hazardous materials, 344, 179- 199. DOI: 10.1016/j.jhazmat.2017.10.014
- 12. Kataeva S.E. 2013. The kinetics of the migration of stabilizers containing lead, out of polyvinylchloride pipes. Vodoochistka. Vodopodgotovka. Vodosnabzhenie, 3(63), 24-28.
- 13. Kida, M., Koszelnik, P. 2021. Investigation of the Presence and Possible Migration from Microplastics of Phthalic Acid Esters and Polycyclic Aromatic Hydrocarbons. Journal of Polymers and the Environment, 29(2), 599-611. DOI: 10.1007/s10924-020-01899-1
- 14. Latini G., De Felice C., Verrotti A. 2004. Plasticizers, infant nutrition and reproductive health review. Reproductive Toxicology, 19(1), 27–33.
- 15. Li M., Li S.H., Xia J.L., Ding C.X., Wang M., Xu L.N., Yang X.H., Huang K. 2017. Tung oil based plasticizer and auxiliary stabilizer for poly(vinyl chloride). Materials & Design, 122, 366-375. DOI: 10.1016/j.matdes.2017.03.025
- 16. Ma Y.F., Liao S.L., Li Q.G., Guan Q., Jia P.Y., Zhou Y.H. 2020. Physical and chemical modifications of poly(vinyl chloride) materials to prevent plasticizer migration – Still on the run. Reactive & Functional polymers, 147, 104458. DOI: 10.1016/j.reactfunctpolym.2019.104458
- 17. Mass Spectral Library – NIST. 2020. Gaithersburg: National Institute of Standards and Technology.
- 18. Mc Lafferty, F.W. 1993. Interpretation of mass spectra. Mill Valley: University Science, 371 p.
- 19. Olkova A., Berezin G. 2021. "Battery of Bioassays" for Diagnostics of Toxicity of Natural Water when Pollution with Aluminum Compounds. Journal of Ecological Engineering, 22(2), 195–199. https://doi.org/10.12911/22998993/131029
- 20. Olkova A.S, Zimonina N.M. 2021. Transformation of Urbanozems in the Areas of Gas Stations. Ecological Engineering & Environmental Technology, 22(3), 51–58. https://doi.org/10.12912/27197050/135448
- 21. Pham L.Q., Uspenskaya M.V., Olekhnovich R.O., Bernal R.A.O. 2021. A Review on Electrospun PVC Nanofibers: Fabrication, Properties, and Application. FIBERS, 9(2), 12. DOI: 10.3390/fib9020012
- 22. Pompili E., Fabrizi C., Fumagalli L., Fornai F. 2020. Autophagy in trimethyltin-induced neurodegeneration. Journal of neural transmission, 127(7), 987- 998. DOI: 10.1007/s00702-020-02210-1
- 23. Prata J.C., da Costa J.P., Lopes I., Duarte A.C., Rocha-Santos T. 2020. Environmental exposure to microplastics: An overview on possible human health effects. Science of the total environment, 702, 134455. DOI: 10.1016/j.scitotenv.2019.134455
- 24. Salazar V., Castillo C., Ariznavarreta C., Campron R., Tresguerres J.A.F. 2004. Effect of oral intake of dibutyl phthalate on reproductive parameters of Long Evans rats and prepubertal development of their offspring. Toxicology. 205(2), 131–137.
- 25. Sheftel' V.O., Kataeva S.E. 1978. The migration of hazardous chemicals from polymeric materials. M.: Khimiya, 168 p.
- 26. Svarc-Gajic J. 2009. General Toxicology. NY, USA: Nova Science Publishers, 287 p.
- 27. Ulker O.C., Ulker O. 2019. Toxicity of Formaldehyde, Polybrominated Diphenyl Ethers (PBDEs) and Phthalates in Engineered Wood Products (EWPs) from the Perspective of the Green Approach to Materials: A Review. Bioresources, 14(3). DOI: 10.15376/biores.14.3.Ulker
- 28. Wypych G. 2020. PVC degradation and stabilization. In: Health & Safety and environmental impact, 4th Edition, Toronto Scarborough, Canada: Chemtec Publishing, p. 431-458, DOI: 10.3390/fib9020012
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-dbe41144-6ca1-48dd-a95a-cd3b3136cb30