Warianty tytułu
Języki publikacji
Abstrakty
Purpose: Evaluation of the influence of plastic deformation and characterization of the electrochemical behaviour of anodized implant rods made of the titanium alloy Ti6Al4V after immersion in air-saturated Ringer’s solution was presented in the paper. Design/methodology/approach: The specimens (dia 6 mm) were anodized and deformed by bending at angle 20o. The comparative characteristics of two zones: the max tensile (I) and the max. compressive stress (II) was based on the determination of electrochemical properties. Impedance spectra (EIS) and corrosion potential measurements were performed on 1, 6, 10 and 16th day after immersion in Ringer`s solution. Findings: Although bending caused an apparent decrease of the protective properties of the anodic layer, the characteristic two-layer anodic film and the values of corrosion potentials were restored due to immersion in Ringer’s solution. The regions of the compressive stresses show the much stronger tendency to restore. Research limitations/implications: The electrochemical tests in Ringer’s solution were performed only in static conditions. Fatigue tests in SBF are in progress. Practical implications: The explanation of the observed phenomena is proposed. Results of the work are of great importance for surgical practice in the pre-operative stage of spinal surgery procedures. Originality/value: Various stress zones formed on implant alloy during bending were described. The results of studies presented in the paper evidenced that changes noticed in the electrochemical behaviour in vitro in Ringer’s solution are advantageous with regard to the protective properties of the investigated alloy.
Słowa kluczowe
Rocznik
Tom
Strony
89--92
Opis fizyczny
Bibliogr. 18 poz., rys., tab., wykr.
Twórcy
autor
- Department of Mechanical Engineering, University of Zielona Gora, ul. Podgorna 50, 65-246 Zielona Gora, Poland, e.krasicka@ibem.uz.zgora.pl
autor
- Department of Mechanical Engineering, University of Zielona Gora, ul. Podgorna 50, 65-246 Zielona Gora, Poland
autor
- Department of Mechanical Engineering, University of Zielona Gora, ul. Podgorna 50, 65-246 Zielona Gora, Poland
Bibliografia
- [1] K. Yamamoto, Y. Kawaguchi, T. Yasunaga, T. Sato, Cracking behavior of AIP-coated metal nitrides under tensile stress, Surface and Coatings Technology 113 (1999), 227.
- [2] A. Kierzkowska, M. Malinowski, E.Krasicka-Cydzik, Effect of bending on anodized Ti6Al4V alloy: I. Surface layers characteristics; this journal, submitted in 2006.
- [3] E. Krasicka-Cydzik, A. Kierzkowska, The effect of bending on the electrochemical behaviour of Ti6Al4V alloy in vitro, Biomaterials Engineering 37 (2004), 53-56.
- [4] J. Marciniak, W. Chrzanowski, J.Zak, Surface structure modification of Ti6Al4V ELI alloy, Biomaterials Engineering 30-33 (2003), 56-58.
- [5] J.R. Goldberg, J.L. Gilbert, The electrochemical and mechanical behavior of passivated and TiN/AlN-coated CoCrMo and Ti6Al4V alloys, Biomaterials 25 (2004), 851.
- [6] Ch. Leinenbach, C. Fleck, D. Eifler, The cyclic deformation behaviour and fatigue induced damage of the implant alloy TiAl6Nb7 in simulated physiological media, Electrochimica Acta 49 (2004), 4563-4576.
- [7] J. Marciniak, Biomaterials, Technical University of Upper Silesia Press, 2002 (in Polish).
- [8] P. Peyre, X. Scherpereel, L. Berthe, Surface modifications induced in 316L steel by laser peening and shot-peening. Influence on pitting corrosion resistance, Matererials Science Engineering 280 (2000), 294-302.
- [9] V. Vignal, C. Valot, R. Oltra, M. Verneau, L. Coudreuse, Analogy between the effects of a mechanical and chemical perturbation on the conductivity of passive films, Corrosion Science 44 (2002), 1477-1496.
- [10] Y.T. Sul, The significance of the surface properties of oxidized titanium to the bone response: special emphasis on potential biochemical bonding of oxidized titanium implant, Biomaterials 24 (2003), 3893–3907.
- [11] D.V. Shtansky, N.A. Gloushankova, A.N. Sheveiko, M.A. Kharitonova, T.G. Moizhess, E.A. Levashov, F. Rossi, Design, characterization and testing of Ti-based multicomponent coatings for load-bearing medical applications, Biomaterials 26 (2005), 2909–2924.
- [12] I.C. Lavos-Valereto,S. Wolynec, Electrochemical impedance spectroscopy characterization of passive film formed on implant Ti-6Al-7Nb alloy in Hank`s solution, Journal of Materials Scence: Materials in Medicine 15 (2004), 55-59.
- [13] Ch. Leinenbach, D. Eifler, Fatigue and cyclic deformation behaviour of surface-modified titanium alloys in simulated physiological media, Biomaterials 2006 Mar; 27(8):1200-8.
- [14] E. Krasicka-Cydzik, Method of formation phosphate layers on titanium and its alloys, PL, Patent filled 367556, 2003.
- [15] E. Krasicka-Cydzik, Formation of thin anodic layers on titanium and its implant alloys in phosphoric acid solutions, Zielona Gora University Press, 2003, (in Polish).
- [16] C. Gabrielli, Tech. Report 4/83, Centre National de la Recherche Scientifique, Uniw. Et M. Curie, 1984.
- [17] T. Burakowski, T. Wierzchon, Surface engineering, Warsaw, 1995, (in Polish).
- [18] A. Kierzkowska, E. Krasicka-Cydzik, M. Jenek, Characteristic surface layer of Ti6Al4V alloy after deformation by bending, Biomaterials Engineering 47-53 (2005), 146-148.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-c9216e17-46e9-45c8-af2e-fe05754d8df9