Semi-organic nonlinear optical material: (((4-sulfonatophenyl)ammonio)oxy)zirconium for dielectric and photonics applications

• Autorzy: Vinoth, E. , Vetrivel, S. , Gopinath, S.
• Języki publikacji: EN

Abstrakty

EN

This article discusses the growth and characterization of (((4-sulfonatophenyl) ammonio)oxy) zirconium (SAOZ) single crystals. Sulphanilic acid incorporated zirconium oxychloride semi-organic single crystals have been synthesized by slow evaporation technique. From the X-ray studies, lattice parameters a = 7.31 Å, b = 7.51 Å, c = 13.92 Å, volume = 765 ų have been found and so the crystal has been identified as orthorhombic with non-centrosymmetric space group P2₁2₁2₁. The powder XRD examination demonstrated the quality and high crystalline nature of the grown crystal. The presence of functional groups was confirmed by FT-IR technique. The chemical structure of the compound was established by ¹H and ¹³C NMR spectra. The optical transmittance window and the low cutoff wavelength of SAOZ have been identified by UV-Vis-NIR studies. Photoluminescence studies showed a wide blue light emission. TG and DTA examinations were carried out to characterize the thermal behavior of the grown crystal. The mechanical strength of the grown crystal was analyzed by the Vickers microhardness test. The elemental analysis was done by EDAX. The dielectric response of the crystals was analyzed in the frequency range of 50 Hz to 5 MHz at various temperatures and the outcomes were discussed. The SHG efficiency was estimated in correlation with KDP by employing powder Kurtz method.

Słowa kluczowe

EN

slow evaporation; SHG efficiency; soft material; dielectric; nonlinear optical

• Czasopismo: Materials Science Poland
• Rocznik: 2020
• Tom: Vol. 38, No. 3
• Strony: 434--442
• Opis fizyczny: Bibliogr. 28 poz., rys., tab.

Twórcy

autor

Vinoth, E.

• Raman Research Laboratory, Post Graduate and Research Department of Physics, Government Arts College, Tiruvannamalai, 606 603, Tamilnadu, India

autor

Vetrivel, S.

• Raman Research Laboratory, Post Graduate and Research Department of Physics, Government Arts College, Tiruvannamalai, 606 603, Tamilnadu, India,

autor

Gopinath, S.

• Raman Research Laboratory, Post Graduate and Research Department of Physics, Government Arts College, Tiruvannamalai, 606 603, Tamilnadu, India

Bibliografia

• [1] LUO H., PAN J., LAR B., LI Y., LI X., HAN L., Inorg. Chem. Commun., 27 (2013), 79.
• [2] WU Q., LI Y., CHEN H., JIANG K., LI H., ZHONG C., CHEN X., QIN J., Inorg. Chem. Commun., 34 (2013), 1.
• [3] CAROLINE L.M., SANKAR R., INDIRANI R.M., VASUDEVAN S., Mater. Chem. Phys., 114 (2009), 490.
• [4] JIANG M.-H., FANG Q., Adv. Mater., 11 (1999), 1147.
• [5] HANUMANTHARAO R., KALAINATHAN S., Spectrochim. Acta A, 86 (2012), 80.
• [6] ROSKAR M.J., CUNNINGHAM P., EWBANK M.D., MARCY H.O., VACHSS F.R., WARREN L.F., GAPPINGER R., BORWICK R., Pure Appl. Opt., 5 (1996), 667.
• [7] LONG N.J., Angew. Chem. Int. Ed., 34 (1995), 21.
• [8] ZYSS J., Molecular nonlinear optics: materials, physics and devices, Academic Press, Boston, 1994.
• [9] MARDER S.R., SOHN J.E., in: STRUCK (Ed.), Materials for Nonlinear Optics, Academic Press, New York, 1991.
• [10] DHANALAKSHMI B., PONNUSAMY S., MUTHAMIZHCHELVAN C., SUBHASHINI V., J. Cryst. Growth, 426 (2015), 103.
• [11] SUBHASHINI V., PONNUSAMY S., MUTHAMIZHCHELVAN C., Spectrochim. Acta Part A, 87 (2012), 265.
• [12] SUBHASHINI V., PONNUSAMY S., MUTHAMIZHCHELVAN C., J. Cryst. Growth, 363 (2013), 211.
• [13] BOOPATHI K., RAJESH P., RAMASAMY P., Mater. Res. Bull., 479 (2012), 2299.
• [14] VETRIVEL S., ANANDAN P., KANAGASABAPATHY K., BHATTACHARYA S., GOPINATH S., RAJASEKARAN R., Spectrochim. Acta Part A, 110 (2013), 317.
• [15] BOOPATHI K., RAMASAMY P., BHAGAVANNARAYANA G., J. Cryst. Growth, (2014), 32.
• [16] BOOPATHI K., RAJESH P., RAMASAMY P., J. Cryst. Growth, 345 (2012), 1.
• [17] CHEMLA D.S., ZYSS J., Nonlinear Optical Properties of Organic Molecules and Crystals, Academic Press, New York, 1987.
• [18] NEWMAN P.R., WARREN L.F., CUNNINGHAM P., CHANG T.Y COOPER., D.E., BURDGE G.L., Mater. Res. Soc. Proc., 173 (1990), 557.
• [19] BADAN J., HIERLE R., PERIGAUD A., ZYSS J., ACS Symp. Series, 233 (1983), 81.
• [20] GARITO A.F., SINGER K.D., Opt. Technol., 18 (1982), 59.
• [21] DASTIDAR P., ROW T.N.G., PRASAD B.R., SUBRAMANIA C.K., Chem. Soc. Perkin Trans., 2 (12) (1993), 2419.
• [22] MYTHILI P., KANAGASEKARAN T., KHAN S.A., KULRIYA P., GOPALAKRISHNANA K., Nucl. Instrum. Phys. Res. B, 266 (2008), 1754.
• [23] VINOTH E., VETRIVEL S., MULLAI U., ARULJOTHI R., GNANAMOORTHY K., J. Adv. Phys., 7 (2018), 1.
• [24] CAROLINE L.M., MANI G., KUMARESAN S., KUMAR M., SELVAN T.S., Rapid Commun., 9 – 10 (2015), 1239.
• [25] SANGWAL K., Mater. Chem. Phys., 63 (2) (2000), 145.
• [26] ONITSECH E.M., Mikroskopie, 95 (1956), 12.
• [27] RAO K., SURENDER V., RANI S., Bull Mater. Sci. B, (2002), 25.
• [28] KURTZ S.K., PERRY T.T., J. Appl. Phys., 39 (1968), 3798.

Identyfikatory

DOI

10.2478/msp-2020-0055