Nanosized MoO3 as a reusable heterogeneous catalyst for the synthesis of 2,6-bis(benzylidene) cyclohexanones

• Autorzy: Dighore, N. R. , Anandgaonker, P. L. , Gaikwad, S. T. , Rajbhoj, A. S.
• Języki publikacji: EN

Abstrakty

EN

Crystalline MoO₃ nanoparticles were obtained by electrochemical synthesis process using tetrapropylammonium bromide as a stabilizer and structure-directing agent in ACN:THF(4:1) solvent. Formation of MoO₃ nanoparticles took place at a constant supply current of 14 mA/cm2. These synthesized MoO3 nanoparticles were characterized by UV-Vis spectroscopy, FT-IR spectroscopy, powder X-ray diffraction (XRD), scanning electron microscopy (SEM). So prepared MoO₃ nanoparticles were used as a heterogeneous catalyst for the synthesis of 2,6-bis(benzylidene)cyclohexanone derivatives. This protocol offers several advantages, such as simple work-up procedure, recyclability of the catalyst, excellent product yield in a short reaction time and purification of products with a non-chromatographic method.

Słowa kluczowe

EN

electrochemical synthesis; MoO3; nanoparticles; heterogeneous catalyst; 2,6-bis benzylidene; cyclohexanone

• Czasopismo: Materials Science Poland
• Rocznik: 2015
• Tom: Vol. 33, No. 1
• Strony: 163--168
• Opis fizyczny: Bibliogr. 38 poz., rys., tab.

Twórcy

autor

Dighore, N. R.

• Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad – 431004 (M.S.), India

autor

Anandgaonker, P. L.

• Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad – 431004 (M.S.), India

autor

Gaikwad, S. T.

• Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad – 431004 (M.S.), India

autor

Rajbhoj, A. S.

• Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad – 431004 (M.S.), India,

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Identyfikatory

DOI

10.1515/msp-2015-0024