Czasopismo
2009
|
[Z] 63, 11-12
|
985-1001
Tytuł artykułu
Autorzy
Wybrane pełne teksty z tego czasopisma
Warianty tytułu
Analytical application of chemiluminescence. Lanthanide(III) ions and their complexes as fluorophores in reaction mixtures
Języki publikacji
Abstrakty
The aim of this review is to evaluate the use of chemiluminescence (CL) as the method for determination of a wide group of organic and inorganic compounds. Chemiluminescence can be defined as the light emission resulting from the transition of an electronically excited state produced in a reaction [1, 2]. CL, in spite of complicated processes occurring in reaction systems, has been used since many years in chemical analysis [13, 22, 30]. Although many chemiluminescence reagents investigated, only a limited number, such as luminol, tris(2,2-bipyridyl)ruthenium(III), potassium permanganate and the Fenton reaction, generating chemical sources of reactive oxygen and nitrogen species, were successfully used for analytical applications. The Fenton system Fe(II)/(III).H2O2 is the source reactive oxygen species and hydrogen radicals [52, 53]. Analytical techniques based on CL have been used in, e.g.: pharmacological studies, clinical and environmental diagnostics [14.17, 22.30, 39.47, 62.65]. Ultra-weak intensity of generated emission (1.104 hn ź s.1 ź cm.2) requires very sensitive detectors and special apparatus, as our detection system for CL measurements based on single photon counting [11]. Studies of CL systems characterised by low intensity of the CL emission require the use of sensitizers. Due to their specific luminescence properties, thelanthanide ions, mainly europium(III) and terbium(III) and their complexes, can be successfully used as chemiluminescence fluorophores [11, 57, 71, 75, 76]. Examples of chemiluminescent methods used for determination of organic molecules (aminoacids, antibiotics, chemotherapeutics), based on the lanthanide(III) ions emission, as a result of the energy transfer process from the excited products of the organic molecule oxidation to the Ln(III), are presented [77, 78].
Czasopismo
Rocznik
Tom
Strony
985-1001
Opis fizyczny
bibliogr. 78 poz., wykr.
Twórcy
autor
autor
- Zakład Ziem Rzadkich, Wydział Chemii, Uniwersytet im. A. Mickiewicza, ul. Grunwaldzka 6, 60-780 Poznań
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS5-0020-0024