Synthesis of 3-chloropropyltrichlorosilane via the catalytic hydrosilylation of allyl chloride with trichlorosilane catalyzed by platinum catalyst - from laboratory scale to pilot plant

• Autorzy: Guliński, J. , Marciniec, B. , Maciejewski, H. , Oczkowicz, S.
• Języki publikacji: EN

Abstrakty

EN

The method for the synthesis of 3-chloropropyltrichlorosilane based on the hydrosilylation of allyl chloride with trichlorosilane in the presence of an original Pt catalytic system has been worked out. The yield and selectivity of Cl(CH2)3SiCl3 depend on the nature of the catalytic system and several other factors (the mode of substrate addition, reaction procedure, etc.)- The optimum reaction conditions were determined. A successful scale-up of the process under study allowed us to implement it on a pilot scale as the first step of the newly emerging Polish low-tonnage organosilane industry.

Słowa kluczowe

PL

hydrosililowanie; chlorek allilu; platyna; katalizatory; zakład doświadczalny

EN

3-chloropropyltrichlorosilane; hydrosilylation; trichlorosilane; allyl chloride; platinum catalyst; pilot plant

• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 1999
• Tom: Vol. 1, nr 1
• Strony: 11-15
• Opis fizyczny: Bibliogr. 38 poz., tab., wykr.

Twórcy

autor

Guliński, J.

autor

Marciniec, B.

autor

Maciejewski, H.

autor

Oczkowicz, S.

• Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland, Fax: [phone],