Warianty tytułu
Konferencja
II International Conference on Advances in Processing, Testing and Application of Dielectric Materials, September, 15-17, 2004, Wrocław
Języki publikacji
Abstrakty
Crystallites developed in steatite ceramics during sintering are the protoenstatite. The size of crystallites depends on temperature. During cooling protoenstatite crystallites invert to clinoenstatite ones, what is the cause of steatite ceramics deterioration and the loss on steatite mechanical endurance. The loss of mechanical endurance is strictly correlated with the degree of proto to clinoenstatite inversion. It was find out that there is much greater tendency for large protoenstatite to invert to clinoenstatite than for small ones. The temperature 1350 °C was find optimal for formation small, well crystallized protoenstatite crystals. This is also the temperature for which the temperature of protoenstatite to clinoenstatite inversion is the lowest and it is 250 °C.
Słowa kluczowe
Rocznik
Tom
Strony
224-228
Opis fizyczny
Bibliogr. 20 poz., rys.
Twórcy
autor
- Institute of Electrotechnics, M.Sklodowskiej-Curie 55/61, 50-369 Wrocław, Poland
autor
- Department of Electrostatics and Electrothermal Engineering, Institute of Heat Engineering and Fluid Mechanics, Wrocław University of Technology, 50-372 Wrocław, Wybrzeże Wyspiańskiego 27, Poland
autor
- Institute of Electrotechnics, M.Sklodowskiej-Curie 55/61, 50-369 Wrocław, Poland
Bibliografia
- [1] SARVER, J.F., HUMMEL, F. A., Stability Relations of Magnesium Metasilicate Polymorphs. J. Am. Ceram. Soc 1962, 55, 152-156.
- [2] ATLAS, L., The Polymorphism of MgSiO3 and Solid —State Equilibrium in the System MgSiO3-CaMgSi2O6. J. Geol. 1952, 60, 125-147.
- [3] FOSTER, W. R., High Temperature X-ray Diffraction Study of the Polymorphism of MgSiO3. J. Am. Ceram. Soc 1951, 34(9), 255-259.
- [4] SHMITH, J.V., The Crystal Structure of Proto-enstatite, MgSiO3. Acta Cryst. 1959,12, 515-519.
- [5] MORIMOTO, N., APPLEMAN, E. D., EVANS, H. T., The Crystal Structures of Clinoenstatite and Pigeonite. Zeitschrift f Krist. 1960,114, 120-147.
- [6] BROWN, W.L., MOROMOTO, N., SMITH, J.W., A structural Explanation of the Polymorphism and Transition of MgSiO3. J. Geol. 1961, 69, 609-616.
- [7] PERROTTA, A. J., STEPHENSON, D. J., Clinoenstatite: High-Low Inversion. Science 1965,148, 1090-1091.
- [8] CHOUDHURY, N., CHAPLOT, S.L., Free Energy and Relative Stability of the Enstatite Mg2Si2O6 Polymorphs. Solid State Com. 2000, 114(3), 127-132.
- [9] GUZEK, Z. Wpływ modyfikacji struktury i tekstury steatytu na jego wytrzymalość mechaniczną. PhD thesis, Electrotechnical Institute, Wrocław, 1974.
- [10] CHAO, M. H. et.al. 'Phase Stability of Chemically Derived Enstatite
- [11] KLUG, H., ALEXANDER, L.X-ray Diffraction Procedures, John Wiley & Sons, NewYork, 1974, pp. 635-642.
- [12] LINDEMAN, W., Beitrag zur Klarung von Strukturen und Stabilitatsbezichungender fur die Electrokeramik wichtigen magnesium haltigen Kettensilikate (Mg-Pyroxene). Sprechsal., 1961, 94, 508-514.
- [13] VERESHCHAGIN, V., GURINA, V., Polymorphism of magnesium Metasilicate and its Role in the Production of Nonaging Steatite Ceramics. Glass and Ceramics, 1997, 54(11-12), 365-67.
- [14] HAERTLING, G., COOK, R., Physical Properties vs Crystalline Phases in Low-Loss Steatite. Adv.in Tech. Ceram., 1963, 30, 47-52.
- [15] MASLENNIKOWA, G.N., FOLGINA, N.P., K woprosom starenija izdielenij iz elektrokieramiczeskich stieatitowych matieriałow. Stiekło, Kieramika 1973, 1, 29-30.
- [16] BLOOR E.G., 'Conversion in steatite ceramics' J.Brit.Ceram Soc., 63, 309-316 (1964)
- [17] ZENER, C., Theory of Growth of Spherical Precipitates from Solid Solution. Trans.A.I.M.E. 1946, 167, 550-557.
- [18] WERT, C., Precipitation from Solid Solutions of C and N in α-Iron. J.Appl.Phys. 1949,20, p.943.
- [19] CHEN, R., On the Calculation of Activation Energies and Frequency Factors from Glow Curves. J. of Appl. Phys., 1969, 40, 570-58. (MgSiO3) Powders. J. Am. Cerant. Soc.,1994, 77(10) 2625-31.
- [20] LEE, W.E., HEUER, A.H., On Polymorphism of Enstatite. J. Am. Ceram. Soc., 1987, 70(5) 349-360.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS3-0006-0005