New Ferrocenylpyridinium Salts with Bulk Second-Order Nonlinear Optical Properties

• Autorzy: Plażuk, D. , Zakrzewski, J. , Nakatani, K.
• Języki publikacji: EN

Abstrakty

EN

Protonation of (E)-1-ferrocenyl-2-(pyridin-4-yl)-ethylene with (+)-camphor-10-sulfonic and picric acid afforded salts displaying high second harmonic generation (SHG) efficiencies (70 and 10 × urea, respectively). Powder X-ray diffraction study confirmed crystallization of these salts in a noncentrosymmetric space group (P2). The electronic structure of the cationic part of the salts was studied by the DFT method.

Słowa kluczowe

EN

ferrocene; pyridinium; nonlinear optics; second harmonic generation; powder X-ray diffraction; DFT

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 12
• Strony: 2105-2111
• Opis fizyczny: Bibliogr. 18 poz., rys.

Twórcy

autor

Plażuk, D.

autor

Zakrzewski, J.

autor

Nakatani, K.

• Department of Organic Chemistry, Faculty of Chemistry, University of Łódź, 90-136 Łódź, Narutowicza 68, Poland,

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