D-Glucosamine Derivatives as Ligands in Highly Enantioselective Palladium-catalyzed Allylic Alkylations

• Autorzy: Bauer, T. , Bartoszewicz, A.
• Języki publikacji: EN

Abstrakty

EN

The rigid derivative of D-glucosamine bearing single diphenylphosphino benzoic acid moiety was synthesized and applied as the ligand for the allylic alkylations. Best results were obtained for 1,3-diphenylpropenyl acetate (up to 96% ee).

Słowa kluczowe

EN

D-glucosamine; allylic alkylation; palladium; enantioselectivity

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 12
• Strony: 2115-2120
• Opis fizyczny: Bibliogr. 16 poz., rys.

Twórcy

autor

Bauer, T.

autor

Bartoszewicz, A.

• Faculty of Chemistry, Warsaw University, ul. Pasteura 1, 02-093 Warszawa, Poland Tel.: [phone] ext.273; fax: [phone],

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