Activated Complex in the Decomposition of N2O over Cu

• Autorzy: Polie, S. , Senegaenik, M. , Kobal, I. , Zieliński, M.
• Języki publikacji: EN

Abstrakty

EN

Decomposition of N2O over Cu wire, at initial N2O pressures 40–60 kPa and temperatures 675–875 K, showed first order kinetics inN2Owith an apparent activation energy of 110 š 16 kJ mol–1. The 15N and 18O kinetic isotope effects under these experimental conditions were determined and interpreted following the Bigeleisen’s formalism. A bent NNO activated complex satisfactorily accounts for the experimental results.

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 11
• Strony: 1729-1729
• Opis fizyczny: –1738, Bibliogr. 102 poz., rys.

Twórcy

autor

Polie, S.

autor

Senegaenik, M.

autor

Kobal, I.

autor

Zieliński, M.

• Stefan Institute, POB 3000, 1000 Ljubljana, Slovenia