Radiation-induced oxidation of thiaproline derivatives in frozen acidic aqueous solutions: theoretical and Electron Spin Resonance study

• Autorzy: Pogocki, D. , Sadło, J.
• Konferencja: Reactive Intermediates in Sulfur Chemistry Workshop dedicated to Professor Klaus-Dieter Asmus on His 60th birthday August 23-26, 1998, Poznan, Poland
• Języki publikacji: EN

Abstrakty

EN

Radicals formed by gamma-radiolysis of thiaproline (thiazolidine-4-carboxylic acid) amino acid and its derivatives in a frozen acidic aqueous solution at 77 K and by subsequent warming from 95 to 200 K have been studied by electron spin resonance (ESR). The experimental parameters of radical spectra were compared with those obtained by quantum-mechanical calculations on AM1 and PM3 semiempirical levels.

Słowa kluczowe

EN

thiaproline; quantum-mechanical calculations; radiolysis; ESR

• Czasopismo: Nukleonika
• Rocznik: 2000
• Tom: Vol. 45, nr 1
• Strony: 101-108
• Opis fizyczny: Bibliogr. 28 poz., rys.

Twórcy

autor

Pogocki, D.

autor

Sadło, J.

• Department of Pharmaceutical Chemistry, University of Kansas, 2095 Constant Avenue, Lawrence, KS 66047, USA