Determination of Thermodynamic and Kinetic Parameters of Inclusion Comnplex Formation of 2-Mercaptobenzothiazole with beta-Cyclodextrin

• Autorzy: Zha, F. , Lu, R.
• Języki publikacji: EN

Abstrakty

EN

The inclusion of 2-mercaptobenzothiazole by beta-cyclodextrin was studied by spectrophotometry. The absorbance of inclusion complex decreased when _-cyclodextrin was dissolved in water and the complex was diluted with ethanol. The same result was obtained by using water as the solvent and diluent. The absorbance decrease in ethanol was greater than that in water. The absorbance increased with the increase of the content of _-cyclodextrin when DMSO was used both as the solvent and diluent. Although the absorbance of the complex was higher than that of the guest when beta-cyclodextrin was dissolved inDMSOand inclusion complex was diluted with water, the absorption decreased when the concentration of beta-cyclodextrin was increased. Stability constants of the inclusion complex in different solvents changed in the order KDMSO < KH2O < KEtOH. Further studies showed that formation of the inclusion complex was spontaneous and exothermic. Thermodynamic parameters and the rate constants of the inclusion reaction were determined.

Słowa kluczowe

EN

beta-cyclodextrin; 2-mercaptobenzothiazole; inclusion complex; thermodynamics; kinetics

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 9
• Strony: 1461-1467
• Opis fizyczny: Bibliogr. 18 poz., rys

Twórcy

autor

Zha, F.

• Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
• College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

autor

Lu, R.

• Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China,
• Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610040, China

Bibliografia

• 1.Elvers B. and Hawkins S., Ullman’s Encyclopaedia of Industrial Chemistry, 5th Edition, Weinheim (1993).
• 2.Chen C.C. and Lin C.E., Anal. Chim. Acta, 321, 215 (1996).
• 3.Bujdakova H., Kuchta T., Sidoova E. and Gvozdjakova A., FEMS Microbiol. Lett., 112, 329 (1993).
• 4.Rennie P.J., Chromatographia, 26, 297 (1988).
• 5.De Wever H., Vereechen K., Stolz A. and Verachten H., Appl. Environ. Microbiol., 64, 3270 (1998).
• 6.Fiehn O., Reemtsma T. and Jekel M., Anal. Chim. Acta, 295, 297 (1994).
• 7.Paxeus N„ Water Res., 30, 1115 (1996).
• 8.De Vos D.E., De Wever H. and Verachten H., Appl. Microbiol. Biotechnol., 39, 622 (1993).
• 9.De Wever H. and Verachten H., Appl. Microbiol. Biotechnol., 42, 623 (1994).
• 10.De Wever H., De Moor K. and Verachten H., Appl. Microbiol. Biotechnol., 42, 631 (1994).
• 11.De Wever H., Van den Neste S. and Verachten H., Environ. Toxicol. Chem., 16, 843 (1997).
• 12.Tolgyessy R, EollarM., Vanco D. and Piatrik M., J. Radioanal. Nucl. Chem., 107, 315 (1980).
• 13.Gaja M.A. and Knapp J.S., Wat. Res., 32, 3786 (1998).
• 14.Mohammad H.H., Shahram T. and Bahram Y., Appl. Cat. B: Environ., 33, 57 (2001).
• 15.Szejtli, Chem. Rev., 98, 1743 (1998).
• 16.Irie T. and Uekama K., J. Pharm. Sci., 86, 147 (1997).
• 17.Conners K.R., Chem. Rev., 97, 1325 (1997).
• 18.Benesi H.A. and Hildebrand J.H., J. Am. Chem. Soc., 71, 2703 (1949).