Spectrochemical Properties of Noncubic Transition Metal complexes in Solutions. XVI. Angular Overlap Treatments of cis-Bis(2,2'-bipyridyl)oxalatechromium(III) Iodide in Aqueous Solution

• Autorzy: Kurzak, K. , Biernacki, K.
• Języki publikacji: EN

Abstrakty

EN

The electronic absorption spectrum of cis-[Cr(ox)(bpy)2]I (bpy = 2,2_-bipyridyl; ox = oxalate ion) of aqueous (H2O) solution, has been measured at room temperature and interpreted using the angular overlap model (AOM), and assuming C2v as the effective symmetry. All the experimental transitions are derived from Gaussian analysis of the solution spectrum. The calculations of the ligand field parameters take into account all the transitions, which are required from the ligand field theory (except those energetically higher than the range of the measured spectrum). The coordination

Słowa kluczowe

EN

angular overlap model; electronic spectra; chromium(III) complexes; 2,2'-bipyridyl; oxalate; molecular structure; low symetry; aqueous solution

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 5
• Strony: 673-679
• Opis fizyczny: Bibliogr. 27 poz. rys.

Twórcy

autor

Kurzak, K.

• Department of Chemistry, University of Podlasie, 08-110 Siedlce, Poland

autor

Biernacki, K.

• Department of Chemistry, University of Podlasie, 08-110 Siedlce, Poland

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