Structural and textural evolution of zirconia nanocrystals induced by thermal treatment

• Autorzy: Adamski, A. , Jakubus, P. , Sojka, Z.
• Języki publikacji: EN

Abstrakty

EN

Nanometric tetragonal and monoclinic zirconia was synthesized from zirconyl chloride by the modified forced hydrolysis method. Phase transitions and morphological changes accompanying zirconia calcination in the temperaure range 600-1000 °C were studied by XRD, HR-TEM techniques and N2-porosimetry. Ageing of the amorphous hydrous zirconia at 100 °C for 48 h in the mother solution and its subsequent calcination at 600 °C for 6 h strongly favoured formation of single-phase tetragonal ZrO2 of the thermal stability enhanced by 250 °C. Influence of the calcination temperature on phase composition, grain size, grain boundaries and pore structure of the resultant ZrO2 material was analyzed.

Słowa kluczowe

EN

nanostructured ZrO2; polymorphism; thermal evolution; grain size

• Czasopismo: Materials Science Poland
• Rocznik: 2008
• Tom: Vol. 26, No. 2
• Strony: 373--380
• Opis fizyczny: Bibliogr. 14 poz.

Twórcy

autor

Adamski, A.

autor

Jakubus, P.

autor

Sojka, Z.

• Jagiellonian University, Faculty of Chemistry, ul. Ingardena 3, 30-060 Cracow, Poland

Bibliografia

• [1] LEE J.-H., J. Mater. Sci., 38 (2003), 4247.
• [2] RAINFORTH W.M., J. Mater. Sci., 39 (2004), 6705.
• [3] YAMAGUCHI T., Catal. Today, 20 (1994), 199.
• [4] MERCERA P.D.L., VAN OMMEN J.G., DOESBURG E.B.M., BURGGRAAF A.J., ROSS J.R.H., Appl. Catal. 57 (1990), 127.
• [5] WELLS A.F., Structural Inorganic Chemistry, Polish Ed., WNiT, Warsaw, 1993.
• [6] JUNG K.T., BELL A.T., J. Mol. Catal. A, 163 (2000), 27.
• [7] GARVIE R.C., J. Phys. Chem., 69 (1965), 1238.
• [8] CHEN S.-G., YIN Y.-S., WANG D.-P., J. Mol. Struct., 690 (2004), 181.
• [9] TANI E., YOSHIMURA M., SŌMYIA S., J. Am. Ceram. Soc., 66 (1983), 11.
• [10] ADAMSKI A., JAKUBUS P., SOJKA Z., Nukleonika 51 (Suppl. 1) (2006), S27.
• [11] PATTERSON A.L., Phys. Rev., 56 (1939), 978.
• [12] CHRASKA T., KING A.H., BERNDT CH.C., Mat. Sci. Eng. A, 286 (2000), 169.
• [13] JAKUBUS P., ADAMSKI A., KURZAWA M., SOJKA Z., J. Therm. Anal. Calorim., 72 (2003) 299.
• [14] ADAMSKI A., JAKUBUS P., SOJKA Z., Solid State Phenom., 128 (2007), 89.