Nanotribological characteristics of lanthanum-based thin films on phosphorylated 3-aminopropyltriethoxysilane self-assembled monolayers

• Autorzy: Qinlin, G. , Cheng, X.
• Języki publikacji: EN

Abstrakty

EN

Lanthanum-based thin films deposited on phosphonate 3-aminopropyltriethoxysilane (APTES) selfassembled monolayers (SAM) were prepared on a hydroxylated silicon substrate by a self-assembling process from a specially formulated solution. Chemical compositions of the films and chemical states of the elements were detected by X-ray photoelectron spectrometry. The thicknesses of the films was determined with an ellipsometer, while their morphologies and nanotribological properties were analyzed by means of atomic force microscopy. It was found that the lanthanum-based thin films showed the lowest friction and adhesion followed by APTES-SAM and phosphorylated APTES-SAM, while silicon substrate showed high friction and adhesion. Microscale scratch/wear studies clearly showed that lanthanumbased thin films were much more scratch/wear resistant than the other samples. The superior friction reduction and scratch/wear resistance of lanthanum-based thin films may be attributed to low work of adhesion of non-polar terminal groups and the strong bonding strength between the films and the substrate.

Słowa kluczowe

EN

lanthanum-based thin films; friction; adhesion; scratch; wear

• Czasopismo: Materials Science Poland
• Rocznik: 2007
• Tom: Vol. 25, No. 4
• Strony: 977--989
• Opis fizyczny: Bibliogr. 27 poz.

Twórcy

autor

Qinlin, G.

autor

Cheng, X.

• School of Mechanical and Power Engineering, Shanghai Jiao Tong University, 200030, Shanghai, PR. China

Bibliografia

• [1] Microelectromechanical Systems: Advanced Materials and Fabrication Methods, NMAB-483, National Academy Press, Washington, DC, 1977.
• [2] ROUKES M., Phys. World, 14 (2001), 25.
• [3] BHUSHAN B., Tribology Issues and Opportunities in Mems, Kluwer Academic, Dordrecht, 1998.
• [4] BHUSHIAN B., Handbook of Micro/Nanotribology, 2nd Ed., CRC, Boca Raton, FL, 1999.
• [5] KAYALI S., LAWTON R., SMITH B.H., IRWIN L.W., EEE Links, 5 (1999), 10.
• [6] ARNEY S., MRS Bull., 26 (2001), 296.
• [7] BHUSHAN B., ISRAELACHVILI J.N., LANDMANN U., Nature, 374 (1995), 607.
• [8] DUGGER M.T., SENFT D.C., NELSO G.C., ACS Symp. Ser., 741 (2000), 455.
• [9] DEPALMA V., TILLMAN N., Langmuir, 5 (1989), 868.
• [10] TSUKRUK V.V., BLIZNYUK V.N., HAZEL J., VISSER D., EVERSON M.P., Langmuir, 12 (1996), 4840.
• [11] BOSHUI C., YI Y., JUNXIU D., J. Chin. Rare Earth Soc., 16 (1998), 220.
• [12] KONISHI Y., SHIMAOKA J.C., ASAI S., React. Funct. Polym., 36 (1998), 197.
• [13] SIDEBOTTOM D.L., HRUSCHKA M.A., POTTER B.G., BROW R.K., J. Non-Cryst. Sol., 222 (1997), 282.
• [14] CHENG X.H., BAI T., WU J., LIANG W., Wear, 260 (2006), 745.
• [15] YU L.G., LIAN Y.F., XUE Q.J., Wear, 214 (1998), 151.
• [16] CHENG X.H., C.Y.XIE, Wear, 254 (2003), 415.
• [17] CHA K.H., KIM D.E., Wear, 251 (2001), 1169.
• [18] BHUSHAN B., Wear, 259 (2005), 1507.
• [19] BUSCHER T.C., MCBRANCH D., DEQUAN L., J. Am. Soc., 118 (1996), 2950.
• [20] KATZ H.E., SCHELLER G., PUTVINSKI T.M., SCHILLING M.L., WILSON W.L., CHIDSEY C.E.D., Science, 254 (1991), 1485.
• [21] BINNIG G., QUATE C.F., GERBER CH., Phys. Rev. Lett., 56(1986), 930.
• [22] GLOSLI J.N., MCLELLAND G.M., Phys. Rev. Lett., 70 (1993), 1960.
• [23] BIERBAUM K., KINZLER M., WÖLL CH., GRUZNE M., HÄHNER G., HEID S., EFFENBERGER F., Langmuir, 11 (1995), 512.
• [24] ISRAELACHVILI J.N., Intermolecular and Surface Forces, Academic Press, New York, 1985.
• [25] BELL T., SUN Y., LIN Z., YAN M., Heat Treat. Met., 27 (2000), 12. Lanthanum-based thin films on phosphorylated APTES monolayers 989
• [26] KANTIPULY C., KATRAGADDA S., CHOW A., Talanta, 37 (1990), 491.
• [27] HUTCHINGS I.M., Tribology, Friction and Wear of Engineering Materials, CRC Press,