Direct synthesis as a new approach to heteropolynuclear complexes

• Autorzy: Kokozay, V. N. , Shevchenko, D. V.
• Konferencja: Sol-Gel Materials Research, Technology, Applications SGM'04, 6-11 june 2004
• Języki publikacji: EN

Abstrakty

EN

The idea of direct synthesis of coordination compounds - use of elemental metals or their oxides as starting materials - has been developed into "Salt route", "Ammonium salt route" and "Direct template synthesis", methods to synthesize heteropolynuclear complexes. The advantages of this approach in obtaining heterobi-, heterotrimetallic and mixed-anion heteropolynuclear coordination compounds are shown taking complexes of transition metals (Cu, Ni, Co, Mn, Zn, Cd) with aminoalcohols and ethylenediamine ligand as an example. The results of the X-ray crystal structure analysis and magnetic properties of the most interesting complexes are presented.

Słowa kluczowe

EN

elemental metals; metal oxides; heteropolynuclear complexes; direct synthesis; crystal structure

• Czasopismo: Materials Science Poland
• Rocznik: 2005
• Tom: Vol. 23, No. 1
• Strony: 287--312
• Opis fizyczny: Bibliogr. 29 poz.

Twórcy

autor

Kokozay, V. N.

• Department of Inorganic Chemistry, National Taras Shevchenko University, Volodymyrska 64, Kyiv 01033, Ukraine

autor

Shevchenko, D. V.

• Department of Inorganic Chemistry, National Taras Shevchenko University, Volodymyrska 64, Kyiv 01033, Ukraine

Bibliografia

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