Polynuclear chain complexes of ruthenium(II,III) pivalate dimers linked by 2,5-dimethyl-N,N'-dicyanobenzoquinonediimine, 1,4-benzoquinone, and 1,4-naphthoquinone

• Autorzy: Yoshioka, D. , Hanada, M. , Mikuriya, M. , Hiromitsu, I.
• Języki publikacji: EN

Abstrakty

EN

Reactions of ruthenium(II,III) pivalate dimer with 2,5-dimethyl-N,N'- dicyanobenzoquinonediimine (2,5-dmdcnqi), 1,4-benzoquinone (1,4-bq), and 1,4- naphthoquinone (1,4-nq) gave polynuclear chain complexes, [Ru2(O2CCMe3)4(L)]nXn, L = 2,5-dmdcnqi, 1,4-bq, and 1,4-nq and X = BF4- and PF6-. It was shown that a weak antiferromagnetic interaction (J = -0.15 cm-1) operates between Ru(II,III) dimers for the 2,5- dmdcnqui complex.

Słowa kluczowe

EN

Ru(II, III) dimer; dicyanobenzoquinonediimine; p-quinones; polymer complexes

• Czasopismo: Materials Science Poland
• Rocznik: 2005
• Tom: Vol. 23, No. 3
• Strony: 765--771
• Opis fizyczny: Bibliogr. 34 poz., rys.

Twórcy

autor

Yoshioka, D.

autor

Hanada, M.

autor

Mikuriya, M.

autor

Hiromitsu, I.

• Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan,

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