Oxidation of heksafluoropropylene using hydrogen peroxide in the presence of phase transfer catalyst

• Autorzy: Meissner, E. , Wróblewska, A.
• Języki publikacji: EN

Abstrakty

EN

The results of the oxidation of hexafluoropropylene (HFP) to hexafluoropropylene oxide (HFPO) using hydrogen peroxide were presented. The oxidation was carried out in the glass reactor at temperatures below -35°C and in the presence of phase transfer catalyst. The influence of: the molar ratio hydrogen peroxide/ HFP, concentration of HFP in methylene chloride and the molar ratio methanol/HFP was investigated.

Słowa kluczowe

PL

heksafluoropropylen; tlenek heksafluoropropylenu; epoksydacja

EN

hexafluoropropylene; hexafluoropropylene oxide; epoxidation

• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2006
• Tom: Vol. 8, nr 2
• Strony: 66-67
• Opis fizyczny: Bibliogr. 7 poz., rys.

Twórcy

autor

Meissner, E.

autor

Wróblewska, A.

• Institute of Organic Chemical Technology, Technical University of Szczecin, ul. Pułaskiego 10, 70-322 Szczecin,

Bibliografia

• (1) Patent RFN 2026677, 1970.
• (2) Eleuterio H. S.: Polymerization of perfluoro epoxides, J. Macromol. Sci. Chem., 1972, A6, 1027.
• (3) Patent US 2614129, 1952.
• (4) Patent US 4902810, 1990.
• (5) Patent US 3775439, 1972.
• (6) Patent RFN 1240516, 1972.
• (7) Hill J. T.: Octafluoroisobutylene oxide derivatives, J. Fluorine Chem., 1977, 9(2), 97.