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2005 | Vol. 7, nr 3 | 77-80
Tytuł artykułu

Seclective methane oxidation to organic derivatives

Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Three methods of methane conversion into oxidants, excluding the stage of obtaining the synthesis gas, are known: partial catalytic oxidation over the heterogeneous catalysts, non-catalytic process of oxidation under pressure and methane esterification combined with hydrolysis. When taking into consideration the results of the studies on methane partial oxidation which have been conducted over a number of years, the last method seems to be the most promising one. The obtained ratio of methane conversion into methanol as the final product, comprises nearly 100% when the process is run in oleum, and platinum chloride (IV) acts as the catalyst.
Wydawca

Rocznik
Strony
77-80
Opis fizyczny
Bibliogr. 19 poz., tab., rys.
Twórcy
  • Szczecin University of Technology, The Institute of Inorganic Chemical Technology, ul. Pułaskiego 10, 70-322 Szczecin, beata.michalkiewicz@ps.pl
Bibliografia
  • (1) Bone W. A., Wheeler R. V.: The slow oxidation of methane at low temperatures, J. Chem. Soc., Trans., 1902, 81, 535.
  • (2) Parmaliana A., Frusteri F., Mezzapica A., Scurrel M. S., Giordano N.: Novel high activity catalyst for partial oxidation of methane to formaldehyde, J. Chem. Soc., Chem. Commun. 1993, 9, 751.
  • (3) Weng T., Wolf E. E.: Partial oxidation of methane on Mo/Sn/P silica supported catalysts, Appl. Catal. 1993, 96, 383.
  • (4) Otsuka K., Wang Y.: Direct conversion of methane into oxygenates Appl. Catal. A 2001, 222, 145.
  • (5) Spencer N. D.: Partial Oxidation of Methane to Formaldehyde by Means of Molecular Oxygen, J.Catal. 1988, 109, 187.
  • (6) Kastsnas G. N., Tsigdios G. A., Schwank J.: Selective Oxidation of Methane over Vycor Glass, Ouartz Glass Various Silisa, Magnesia and Alumina Surfaces, Appl. Catal. 1989, 44, 33.
  • (7) Alptakin G. O., Herring A. M., Williamson D. L., Ohno T. R., McCormick R. L.: Methane Partial Oxidation by Unsupported and Silica Supported Iron Phosphate Catalysts: Influence of Reaction Conditions and Co-Feeding of Water on Activity and Selectivity, J. Catal. 1999, 181, 104.
  • (8) Kałucki K., Michalkiewicz B.: Partial Oxidation of Methane to Formaldehyde over a Mo-O/SiO2 Catatyst, Polish Journal of Chemical Technology, 2000, 2, 17.
  • (9) Kałucki K., Michalkiewicz B.: The effect of Boron and Magnesium Additives on Catalytic Perform of Mo-O/SiO2 in the Partial Oxidation of Methane, Polish Journal of Chemical Technology, 2001, 3, 16.
  • (10) Michalkiewicz B.: Partial oxidation of methane to formaldehyde and methanol using molecular oxygen over Fe-ZSM-5, Appl. Catal. 2004, 277, 147.
  • (11) Burch R., Squire G. D., Tsang S. C.: Direct conversion of methane into methanol, J. Chem. Soc, Faraday Trans 1, 1989, 85, 3561.
  • (12) Lott J. L., Sliepcevich C. M.: Partial oxidation of methane at high pressures, Ind. Eng. Chem. Proc. Des. Develop., 1967, 67, 67.
  • (13) Rytz D. W., Baiker A.: Partial Oxidation of Methane to Methanol in a Flow Reactor at Elevated Pressure, Ind. Eng. Chem. Res., 1991, 30, 2287
  • (14) Michalkiewicz B., Ziebro J.: Non-Classical Prospective Methods of Getting Methanol and Formaldehyde, Inżynieria Chemiczna i Procesowa, 2004, 25, 1973.
  • (15) Shilov A. E., Shul'pin G. B.: Activation of C-H Bonds by Metal Complexes, Chem. Rev. 1997, 97, 2879.
  • (16) Periana R. A., Taube D. J., Gamble S., Taube H., Satoh T., Fujii H.: Platinum catalysts for the High-Yield Oxidation of Methane to a Methanol Derivative, Science, 1998, 280, 560.
  • (17) Vargaftik M. N., Stolarov I. P., Moiseev I. L.: Highly selective partial oxidation of methane to methyl trifluoroacetate, J. Chem. Soc, Chem. Commun. 1990, 15, 1049.
  • (18) Periana R. A., Taube D. J., Evitt E. R., Löffler D. G., Wentrcek P. R., Voss G., Masuda T.: A Mercury-Catalyzed, High-Yield System for the Oxidation of Methane to Methanol, Science, 1993, 259, 340.
  • (19) Michalkiewicz B., Kałucki K., Sośnicki J. G.: Catalytic system containing metallic palladium in the process methane partial oxidation, Journal of Catalysis, 2003, 215,14.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0034-0102
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