Warianty tytułu
Języki publikacji
Abstrakty
Reactions of MoS(2)/(4), MoO(2)S(2)(2-), MoO(2)(4), ReSJ, ReO-(4), VS(3)/(4), and VO(3-)(4) with CS(2) are described. The syntheses and X-ray determinations of (NEt(4))(2) [Mo2(S)(2) (Mo(2) S)(2) (u -S)(2)], space group P2(1)/C, a = 9.3169(3) A,b = 16.3211(5) A, c = 22.8415(5) A, Beta = 92.590(1)°, V = 3469.8(2) A3, R = 0.0898 for 8720 independent reflections and (NEt(4))(2)[Mo(2)(O)(2)(Mi - S)(mi - O)(n(2) - COS(2)2] 0.5 CS(2), space group P2(1)/C, a = 9.8190(1) A, b = 20.6313(13) A, c = 15.7193(3) A, Beta = 92.353(1)°, V = 3181.71(8) A(3), R = 0.0576 for 5760 independent reflections are presented. A rationalization of the syntheses is discussed and the structure of (NH4)[HCOS(2) is described, space group Pca2i, a = 8.3174(9) A, b = 5.6562(6) A, c = 10.7125(12) A, V = 503.97(9) A3, R = 0.0402 for 952 independent reflections. (13)C NMR data for trithiocarbonate and dithiocarbonate complexes are presented.
Słowa kluczowe
Rocznik
Tom
Strony
15-25
Opis fizyczny
Bibliogr. 40 poz.
Twórcy
autor
autor
autor
- IREM, Institut Lavoisier UMR C 8637, Universite de Versailles, 45 Avenue des Etatsunis, 78035 Versailles Cedex, France
Bibliografia
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-article-BPP1-0030-0003