Warianty tytułu
Kinetyka procesu syntezy katalitycznej ETBE w reaktorze trójfazowym
Języki publikacji
Abstrakty
A three-phase reactor with an air stream controlled by a draft tube was applied to ETBE synthesis from isobutene and ethanol under atmospheric pressure in the presence of Amberlyst 15 resin. It was found that when excess of ethanol was used, the catalytic reaction was highly selective and proceeded as 1st order towards isobutene. The reaction product, ETBE, if not removed from the mixture, retarded the reaction rate.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
11-19
Opis fizyczny
Bibliogr. 21 poz., Rys. 8
Twórcy
autor
- Faculty of Commodity Science, Poznań University of Economics, al. Niepodległości 10,60-967 Poznań, Poland
autor
- Faculty of Commodity Science, Poznań University of Economics, al. Niepodległości 10,60-967 Poznań, Poland, sobczynski@novcil.ae.poznan.pl
Bibliografia
- [1] K.L. JENSEN and R. DATIA, Ind. Eng. Chem. Res., 34, 392 (1995).
- [2] L. SOLA,M.A. PERICAS, F. CUNILL and J. TEJERO, Ind. Eng. Chem. Res., 34, 3718 (1995).
- [3] C. FITE, M. IBORRA,J. TEJERO and F. CUNILL, Ind. Eng. Chem. Res., 33, 581 (1994).
- [4] O. FRANCOISSE and F.C. THYRION, Chem. Eng. Process., 30, 141 (1991).
- [5] J. IZQUIERDO,F. CUNILL,M. VILA, M. IBORRA and J. TEJERO, Ind. Eng. Chem. Res., 33, 2830 (1994).
- [6] L. SOLA, M. PERICAS, F. CUNILL and M. IBORRA, Ind. Eng. Chem. Res., 33, 2578 (1994).
- [7] D. PARRA, J. TEJERO,F. CUNILL,M. IBORRA and J. IZQUIERDO, Chem. Eng. Sci., 49, 4563 (1994).
- [8] F. CUNILL, M. VILLA, J. IZQUIERDOM. , IBORRA and J. TEJERO, Ind. Eng. Chem. Res., 32, 564 (1993).
- [9] M. VILLA, F. CUNILL, J. IZQUIERDO, J. TFJERO and M. IBORRA, Chem. Eng. Comm., 124,223 (1993).
- [10] X. YIN, B. YANG and S. GOTO, Int. J. Chem. Kinet., 27, 1065 (1995).
- [11] C. GOMEZ,F. CUNILL, M. IBORRA, J. IZQUIERDO and J. TEJERO, Ind. Eng. Chem. Res., 36, 4756 (1997).
- [12] M. IBORRA, J. IZQUIERDO, J. TEJERO and F. CUNILL, Chemtech., 88,120 (1988).
- [13] A. QUITAN, H. ITOH and S. GOTO, J. Chem. Eng. Jap., 34,539 (1999).
- [14] M. IBORRA,J. IZQUIERDO, J. TEJERO and F. CUNILL, J. Chem. Eng. Data., 34, 1 (1989).
- [15] K. SUNDMACHER,R-S. ZHANG and U. HOFFMANN, Chem. Eng. Technol., 18,269 (1995).
- [16] S. FISCHER and R. KUNIN, Anal. Chem., 27, 1191 (1955).
- [17] A. SOBCZYŃSKI, J. GIMENEZ and S. CERVERA-MARCH, Pol. J. Appl. Chem., 40, 103 (1996); Monatsh. Chem., 128, 1109 (1997).
- [18] R.M. ECCLES and G.R. de VAX, Chem. Eng. Prog., 77,80 (1981).
- [19] R. STEINER, Chem. Eng. Process., 21, 1 (1987),
- [20] L.S. FAN, S.J. HWANG and A. MATSUURA, Chem. Eng. Sci., 39, 1677 (1984).
- [21] M. VILA, C. FITE, M. IBORRA, F. CUNILL, J.F. IZQUIERDO and J. TEJERO, in: Proc. 6th Mediterranean Congr. Chem. Eng., Barcelona 1993, p. 209.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-article-BPP1-0026-0002