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2009 | Vol. 37, nr 2 | 286-291
Tytuł artykułu

Application of microwave/radio frequency and radio frequency/magnetron sputtering techniques in polyurethane surface modification

Wybrane pełne teksty z tego czasopisma
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The aim of the study is the analysis of the possibilities of application of MW/RF PACVD and RF PACVD/MS systems in polyurethane surface modification. Design/methodology/approach: As the substrates samples made out of the biocompatibile polyurethane were used. Modifications were performed in MW/RF PACVD and RF PACVD/MS reactors using different gases and process parameters. Topography, thickness and contact angle were measured using Atomic Force Microscopy, Profilometry and Contact Angle Measuring Instrument. Findings: Optimal plasma parameters ensuring deposition of carbon layers without surface degradation were worked out. Deposited layers were less than 500 nm thick and presented the wetting angle value more than 90ş. During the examinations the influence of the gas atmosphere and process parameters used for the preliminary substrates modification were investigated. Obtained results prove the possibility of application of MW/RF PACVD and RF PACVD/MS techniques in deposition of carbon-based coatings on polyurethane substrates used for artificial heart chambers manufacturing. Research limitations/implications: Modification of polymer surface has to be conducted at low temperatures, up to 100şC. Unfortunately not all CVD and PVD methods used in this field guarantee the adequate adhesion of manufactured layers deposited in such low temperatures. So far the most promising results were obtained with use of PLD (pulsed laser deposition) techniques. However application of MW (microwave) low temperature plasma source and combination of magnetron sputtering technique with RF (radio frequency) plasma source seems to be equally interesting techniques. Originality/value: Optimization of carbon layers deposition techniques on polyurethane substrates can be helpful in improvement of modern artificial heart chambers construction. All investigation results obtained in his field attend to work out the new generation of cardiosurgical implants within the confines of multiyear Project „Polish Artificial Hart”.
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Wydawca

Rocznik
Strony
286-291
Opis fizyczny
Bibliogr. 12 poz., rys., tabl.
Twórcy
autor
  • Institute of Materials Science and Engineering, Technical University of Lodz, ul. Stefanowskiego 1/15, 90-924 Łódź, Poland, witold.kaczorowski@gmail.com
Bibliografia
  • [1] Ch. Oehr, Plasma surface modification of polymers for biomedical use, Nuclear Instruments and Methods in Physics Research B 208 (2003) 40-47.
  • [2] I.-H. Loh, Plasma surface modification in biomedical applications, Medical Device Technology 10/1 (1999) 24-30.
  • [3] A. Baron, D. Szewieczek, R. Nowosielski, Selected manufacturing techniques of nanomaterials, Journal of Achievements in Materials and Manufacturing Engineering 20 (2007) 83-86.
  • [4] R. Major, J. Bonarski, J. Morgiel, B. Major, E. Czarnowska, R. Kustosz, J. M. Lackner, W. Waldhauser, Elastic TiN coating deposited on polyurethane by pulsed laser, Surface and Coatings Technology 200 (2006) 6340-6345.
  • [5] W. Kaczorowski, P. Niedzielski, Morphology and Growth Process of Carbon Films Prepared by Microwave / Radio Frequency Plasma Assisted CVD, Advanced Engineering Materials 10/7 (2008) 651-656.
  • [6] W. Kaczorowski, Carbon layers manufactured in two-frequency plasma, PhD Thesis, Łódź, 2005 (in Polish).
  • [7] D. Batory, T. Blaszczyk, M. Clapa, S. Mitura, Investigation of anti-corrosion properties of Ti:C gradient layers manufactured in hybrid deposition system, Journal of Materials Science 43/10 (2008) 3385-3391.
  • [8] D. Batory, Gradient carbon layers a-C:H/Ti manufactured in hybrid plasma methods RF PACVD/MS, PhD Thesis, Łódź, 2008 (in Polish).
  • [9] M. Cłapa, D. Batory, Improving adhesion and wear resistance of carbon coatings using Ti:C gradient layers, Journal of Achievements in Materials and Manufacturing Engineering 20 (2007) 415-418.
  • [10] Z. Rożek, W. Kaczorowski, D. Lukáš, P. Louda, S. Mitura, Potential applications of nanofiber textile covered by carbon coatings, Journal of Achievements in Materials and Manufacturing Engineering 27/1 (2008) 35-38.
  • [11] J. Grabarczyk, D. Batory, P. Louda, P. Couvrat, I. Kotela, K. Bakowicz, S. Mitura, Carbon coatings for medical implants, Journal of Achievements in Materials and Manufacturing Engineering 20 (2007) 107-110.
  • [12] R. M. Nowak, S. Jonas, S. Zimowski, K. Tkacz-Śmiech, Amorphous carbon layers on polymeric substrates, Journal of Achievements in Materials and Manufacturing Engineering 25/1 (2007) 23-26.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS2-0021-0022
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