Czasopismo
2012
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Vol. 48, iss. 1
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63-76
Tytuł artykułu
Autorzy
Wybrane pełne teksty z tego czasopisma
Warianty tytułu
Języki publikacji
Abstrakty
A new method of obtaining a ZnO-SiO2 synthetic composite from emulsion systems is described. The reagents were solutions of sodium silicate and zinc sulphate, cyclohexane was used as an organic solvent and non-ionic surfactants as modifiers. The influence of the mode of reagents dosing and type of emulsifiers on the physicochemical properties, structure and particle size of ZnO-SiO2 was evaluated. The choice of the optimum emulsifier or mixture of emulsifiers and their amounts needed for the process of precipitation and ensuring getting products of uniform particles and the smallest possible size was proposed. The ZnO-SiO2 composite obtained was characterised by micrometric particle size. The oxide composites obtained were subjected to thorough analyses to determine their physicochemical properties, dispersion and morphology. Particle size distributions were evaluated by the NIBS technique and laser diffraction method. The products were also characterised by sedimentation profiles, wettability with water and colorimetric analyses, determination of bulk density or ZnO and SiO2 contents.
Rocznik
Tom
Strony
63-76
Opis fizyczny
Bibliogr. 21 poz.
Twórcy
autor
autor
- Poznan University of Technology, Institute of Chemical Technology and Engineering M. Sklodowskiej-Curie 2, PL-60965 Poznan, teofil.jesionowski@put.poznan.pl
Bibliografia
- 1. CANNAS C., CASU M., LAI A., MUSINO A., PICCALUGA G., 1999, XRD, TEM and 29Si MAS NMR study of sol-gel ZnO-SiO2 nanocomposites, J. Mater. Chem., 9, 1765–1769.
- 2. CHAKRABARTI S., GANGULI D., CHAUDHURI S., 2004, Excitonic and defect related transitions in ZnO-SiO2 nanocomposites synthesized by sol-gel technique, Phys. Status Solidi, 201, 2134-2142.
- 3. FOTOPOULOS A. P., TRIANTAFYLLIDIS K. S., 2007, Ethylene epoxidation on Ag catalyst supported on non-porous, microporous and mesoporous silicates, Catal. Today, 127, 148–156.
- 4. FU Z., YANG B., LI L., DONG W., JIA C., WU W., 2003, An intense ultraviolet photoluminescence in sol-gel ZnO-SiO2 nanocomposites, J. Phys. Condens. Mat., 15, 2867–2873.
- 5. GANGULI D., CHATTERJEE M., 1997, Ceramic Powder Preparation: A Handbook, Kluwer, Boston.
- 6. JESIONOWSKI T., 2009, Preparation of spherical silica in emulsion systems using the co-precipitation technique, Mater. Chem. Phys., 113, 839–849.
- 7. KALINKIN A. M., KALINKINA E. V., ZALKIND O. A., 2009, Mechanosorption of carbon dioxide by Ca- and Mg-containing silicates and alumosilicates sorption of CO2 and structure-related chemical changes, Colloid J., 71, 185-192.
- 8. KRYSZTAFKIEWICZ A., LIPSKA L. K., CIESIELCZYK F., JESIONOWSKI T., 2004, Amorphous magnesium silicate – synthesis, physicochemical properties and surface morphology, Adv. Powder Technol., 15, 549–565.
- 9. LAURENTOWSKA A., CIESIELCZYK F., JÓŹWIAK K., JESIONOWSKI T., 2010, Syntetyczne kompozyty tlenkowe typu ZnO-SiO2 o dużym stopniu zdyspergowania, Przem. Chem., 89, 1351–1356.
- 10. LEE S. G., JANG Y. S., PARK S. S., KANG B. S., MOON B. Y., PARK H. C., 2006, Synthesis of fine sodium-free silica powder from sodium silicate using w/o emulsion, Mater. Chem. Phys., 100, 503-506.
- 11. MICHALSKA I., KRYSZTAFKIEWICZ A., BOGACKI M. B., JESIONOWSKI T., 2003, Preparation and characterisation of precipitated zinc silicates, J. Chem. Technol. Biot., 78, 452-460.
- 12. MIDMORE B. R., 2001, Interaction between colloidal silica and a nonionic surfactant hexagonal liquid crystalline phase, Colloids Surf. A, 182, 83–92.
- 13. MO C. M., LI Y. H., LIU Y. S., ZHANG Y., ZHANG L. D., 1998, Enhancement effect of photoluminescence in assemblies of nano-ZnO particles/silica aerogels, J. Appl. Phys., 83, 4389–4391.
- 14. ROBINS M. M., WATSON A. D., WILDE P. J., 2002, Emulsions – creaming and rheology, Curr. Opin. Coll. Interface Sci., 7, 419–425.
- 15. SOMASUNDARAN P., MEHTA S. C., PUROHIT P., 2006, Silicone emulsion, Adv. Colloid Interface Sci., 128–130, 103–109.
- 16. SÓJKA-LEDAKOWICZ J., OLCZYK J., WALAWSKA A., LAURENTOWSKA A., KOŁODZIEJCZAK-RADZIMSKA A., JESIONOWSKI T., 2010, Modyfikacja wyrobów włókienniczych przy wykorzystaniu tlenku cynku o cząstkach nanometrycznych oraz kompozytu tlenkowego ZnO-SiO2, Przem. Chem., 89, 1648–1652.
- 17. SUN Q., VRIELING E. G., VAN SANTEN R. A., SOMMERDIJK N. A. J. M., 2004, Bioinspired synthesis of mesoporous silicas, Curr. Opin. Solid St. M., 8, 111–120.
- 18. YANG Y., ZHUANG Y., HE Y., BAI B., WANG X., 2010, Fine tuning of the dimensionality of zinc silicate nanostructures and their application as highly efficient absorbents for toxic metal ions, Nano Res., 3, 581–593.
- 19. YAO B. D., SHI H. Z., BI H. J., ZHANG L. D., 2000, Optical properties of ZnO loaded in mesoporous silica, J. Phys.: Condens. Matter, 12, 6265–6270.
- 20. YING J. Y., MEHNERT C. P., WONG M. S., 1999, Synthesis and applications of supramolecular-templated mesoporous materials, Angew. Chem. Int. Edit., 38, 56–77.
- 21. ZHAO S., JI Z., YANG Y., HUO D., LV Y., 2007, Nano-ZnO embedded SiO2 glass with intense ultraviolet emission, Mater. Lett., 61, 2547–2550.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT2-0003-0059