Study of Submicron Structured Energetic Coordination Metal Complexes for Laser Initiation Systems Condensed Phase Leading Reaction

• Autorzy: Ilyushin, M. A. , Tselinsky, I. V. , Ugryumov, I. A. , Dolmatov, V. Yu. , Shugalei, I. V.
• Języki publikacji: EN

Abstrakty

EN

Development of condensed energetic systems, especially photosensitive primary explosives for the systems of laser initiation is one of the foremost fields of application of energetic materials. There have been synthesized and investigated a coordination complex of mercury(II) chlorate(VII) with 5-hydrazinotetrazole as ligand (compound (I)) as a potential photosensitive primary explosive. This complex consisting of particles of 1.1 0.8 m size demonstrated the highest sensitivity to laser irradiation combined with an extremely low initiation threshold. On the basis of compound (I) a photosensitive formulation EC-2 containing ∼ 90% of the complex mercury(II) chlorate(VII) and ∼ 10% of an optically transparent polymer as an inert matrix has been proposed. Formulation EC-2 has extremely high sensitivity to Q-switch IR-laser irradiation. Formulation EC-2 with added ultra disperse diamonds (UDD) has shown lower initiation thresholds in comparison with neat EC-2 or EC-2 with added submicron black carbon, fullerens or nanotubes instead of UDD.

Słowa kluczowe

EN

perchlorate complex; threshold of initiation; IR-laser; pulse; UDD

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2005
• Tom: Vol. 2, nr 1
• Strony: 21-33
• Opis fizyczny: Bibliogr. 25 poz.

Twórcy

autor

Ilyushin, M. A.

• St.-Petersburg State Institute of Technology (Technical University) 190013 Moskovsky pr. 26, Russia Fax: [phone],

autor

Tselinsky, I. V.

• St.-Petersburg State Institute of Technology (Technical University) 190013 Moskovsky pr. 26, Russia Fax: [phone]

autor

Ugryumov, I. A.

• St.-Petersburg State Institute of Technology (Technical University) 190013 Moskovsky pr. 26, Russia Fax: [phone]

autor

Dolmatov, V. Yu.

• St.-Petersburg State Institute of Technology (Technical University) 190013 Moskovsky pr. 26, Russia Fax: [phone]

autor

Shugalei, I. V.

• St.-Petersburg State Institute of Technology (Technical University) 190013 Moskovsky pr. 26, Russia Fax: [phone]

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