Preparation, Properties and Application of Energetic Complex Perchlorates of d-Metals

• Autorzy: Ilyushin, M. A. , Tselinsky, I. V. , Bachurina, I. V. , Gruzdev, Y. A. , Sinditskii, V. P. , Serushkin, V. V. , Egorshev, V. Y.
• Języki publikacji: EN

Abstrakty

EN

Methods for the synthesis of novel energetic complex perchlorates of d-metals have been developed. According to derivatographic analysis data, the complexes are thermally stable compounds. One of the promising ways of regulating ballistic characteristics of highly filled energetic formulations is the introduction of burn modifiers. Complex compounds of d-metals are known to be effective modifiers of the process of burning. Ballistic tests were made in a constant pressure bomb and demonstrated that the prepared compounds are promising modifiers of the burn rate and can be used in the developed formulations of rocket propellants.

Słowa kluczowe

EN

complex perchlorates; 1,5-pentamethylenetetrazole; modifiers of burning; derivatographic analysis; drop hammer test; ballistic test; bomb of constant pressure

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2006
• Tom: Vol. 3, nr 4
• Strony: 41-49
• Opis fizyczny: Bibliogr. 5 poz.

Twórcy

autor

Ilyushin, M. A.

autor

Tselinsky, I. V.

autor

Bachurina, I. V.

autor

Gruzdev, Y. A.

autor

Sinditskii, V. P.

autor

Serushkin, V. V.

autor

Egorshev, V. Y.

• Saint-Petersburg State Institute of Technology (Technical University), 26 Moskovsky pr., Saint-Petersburg, Russia,

Bibliografia

• [1]IlyushinM.A.,ZhilinA.Yu.,TselinskyI.V.,NikitinaYu.A.,KozlovA.S.,ShugaleiI.V, Energetic ammine cobalt (III) perchlorates with cyclopentamethylentetrazole as ligand, Russian Journal of Applied Chemistry, 2005, 75(2), 195-199 (in Russian).
• [2] Ilyushin M. A., Smimov A. V., Kotomin A. A., Tselinsky I. V, Coordination complexes as inorganic explosives for initiation systems, Hanneng Cailiao^Energetic materials, 1994, 2(1), 16-20.
• [3] FogelzangA.E., Egorshev V. YU., SinditskyV. P., Serushkin V. V., SaclantyA. R.,Astudy of burning behavior of chemical analogs of explosive CP, Proc. 18-th International Pyrotechnics Seminar, Chicago, Illinois, 13-15 July 1992, p. 303-320.
• [4] Dudyrev A. S., Tselinsky I. V., Ilyushin M. A., Chapter 6, Technology of energetic materials and products on their base in: Chemical technologies, Ed. P. D. Sarkisov, Ministry of Education of Russia, D. I. Mendeleev Russian University of Chemical Technology Moscow 2003, pp. 403-488 (in Russian).
• [5] Ilyushin M. A., Tselinsky I. V, Bachurina I. V., Novoselova L. O., Konyushenko E. N., Kozlov A. S., Gruzdev Yu. A., Application of energy-saturated complex perchlorate, International Conference "Zababakhin scientific talks", September 5-10, 2005, Snezhinsk, Chelyabinsk Region, Russia 2005, p. 83-84.