Breakdown of the born-oppenheimer approximation in InCl X(1)Sigma(+) electric state

• Autorzy: Molski, M. , Konarski, J.
• Języki publikacji: EN

Abstrakty

EN

Pure rotational transitions of (115)In(35)Cl, (115)In(37)Cl, (113)In(35)Cl and (113)In(37)Cl were analyzed to yield mass-independent radial parameters representing the internuclear potential energy and nonadiabatic rotational effect of the nuclei. From the determined t(In,Cl)-0 parameters, reflecting the purely the nonadiabatic rotational effect, and from experimental value of the dipole moment the rotational g-factor of four isotopic variants of InCl has been evaluated. The quality of the Born-Oppenheimer approximation and the extent of its breakdown in indium monochloride have been examined.

Słowa kluczowe

EN

non-adiabatic effects; rotational transitions; Born-Oppenheimer approximation; indium monochloride

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 7S
• Strony: 1398-1404
• Opis fizyczny: Bibliogr. 24 poz., tab.

Twórcy

autor

Molski, M.

autor

Konarski, J.

• Department of Theoretical Chemistry Faculty of Chemistry Adam Mickiewicz University ul. Grunwaldzka 6 60-780 Poznań Poland