Spectroscopic properties of new indium(III) phthalocyanine complexes

• Autorzy: Janczak, J.
• Języki publikacji: EN

Abstrakty

EN

New blue-violet diamagnetic diindium(III) triphthalocyanine and paramagnetic indium(III) diphthalocyanine complexes have been obtained in crystalline form. The UV-VIS, IR and far IR spectra of the I-n2P-c3 and I-nP-c2 complexes are presented here for the first time. The spectroscopic data of the both In(III) complexes are discussed in terms of characteristic group frequencies and compared with other phthalocyanines. An emperical vibrational assignment of the observed fundamentals is given. The absorption electronic spectra indicate the proximity of the HOMO and LUMO of the Pc ligand in energy.

Słowa kluczowe

EN

electronic and vibrational spectroscopy; indium(III) phthalocyanines; metallophthalocyanines; sandwich-type phthalocyanine; complexes

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1998
• Tom: Vol. 72, nr 8
• Strony: 1871-1878
• Opis fizyczny: Bibliogr. 41 poz., tab., wykr.

Twórcy

autor

Janczak, J.

• W. Trzebiatiwski Institute of Low Temperature and Structure Research Polish Academy of Sciences Okólna 2 str. P.O.Box 937 50-950 Wrocław Poland